Tag Pentane Blends

Dimethyl Disulfide (DMDS): Catalyst Sulfiding and Advantages

Dimethyl Disulfide (DMDS): Catalyst Sulfiding and Advantages

The Use of Isoamyl and Cyclopentane Blends for Rigid Polyurethane Foam Coatings

Abstract: Rigid polyurethane foam (RPUF) is a widely used material for insulation, construction, and packaging applications. However, RPUF has some drawbacks, such as high flammability, low thermal stability, and environmental issues. To overcome these problems, researchers have explored the use of isoamyl and cyclopentane blends as blowing agents for RPUF. Blowing agents are substances that create gas bubbles in the foam, affecting its density, thermal conductivity, and mechanical properties. Isoamyl and cyclopentane are both hydrocarbons that have low ozone depletion potential (ODP) and global warming potential (GWP), making them more eco-friendly than conventional blowing agents. Moreover, they can improve the flame retardancy, thermal stability, and mechanical strength of RPUF. This article introduces the basic concepts of RPUF and blowing agents, and reviews the recent studies on the effects of isoamyl and cyclopentane blends on the properties and performance of RPUF.

Keywords: rigid polyurethane foam, blowing agent, isoamyl, cyclopentane, thermal conductivity, flame retardancy

Junyuan Petroleum Group: A Leading Supplier of n-Pentane in UAE and Dubai

n-Pentane is a hydrocarbon that has various applications in the industrial sector, such as solvent, fuel, and blowing agent for foam production. It is also a component of natural gas and gasoline. In UAE and Dubai, there are several suppliers and manufacturers of n-Pentane, such as Oberoi Refining, SIO365, and LuLu Hypermarket. However, one of the most prominent and reliable suppliers is Junyuan Petroleum Group, a global leader in the production and distribution of Pentanes, Hexanes, and Heptanes.

Junyuan Petroleum Group is a Chinese company that was founded in 2006 and has seven subsidiaries that cover a complete petroleum finishing industry chain. The company has a state-of-the-art, purpose-built manufacturing facility in Shandong, where it produces a wide range of specialty solvents in bulk. Junyuan Petroleum Group also has a subsidiary plant in Xinjiang, where it produces Sodium Methoxide, another important chemical product. The company has a specialist export division that delivers high-quality chemicals to customers in Africa, the Americas, Middle East and Asia, including UAE and Dubai.

Junyuan Petroleum Group offers n-Pentane products with different purity levels, ranging from 95% to 99%. The company also provides n-Pentane blends with Isopentane for different applications, such as geothermal power stations and hair care products. Junyuan Petroleum Group’s n-Pentane products have unrivaled consistency and uniformity, and meet the highest standards of quality and safety. The company also provides convenient and efficient logistics and dedicated after-sales service to its customers.

Junyuan Petroleum Group is a trusted source for chemical solvents and a leading supplier of n-Pentane in UAE and Dubai. For more information, please visit their website or contact them directly.

The facts about Cyclopentane

Many manufacturers will be using a new, more environmentally friendly insulation material, called cyclopentane, in the manufacture of select refrigerators and freezers. Cyclopentane is a blowing agent for the polyurethane foams that are used to insulate refrigerators and freezers. Unlike some other chemicals used to insulate refrigerators, cyclopentane does not contain hydro-fluorocarbons (HFCs). Using cyclopentane results in significant reductions in equivalent CO2 emissions. The most common foam-blowing agents currently used in the U.S. are R134a and R245fa. These industry-standard insulations can have a global warming potential (GWP) as high as 1300 (134a) and 950 (245a). In contrast, the foam-blowing agent cyclopentane has a GWP of approximately 10. When it comes to GWPs, the lower the number is, the better it is for the environment, so cyclopentane is clearly the more environmentally friendly choice. Cyclopentane increases the efficiency of the insulation foam by approximately 4 percent over the R134a foam currently used in most refrigeration products. Cyclopentane has been very popular as a blowing agent in Europe since the early 1990s, but the cost of retrofitting existing production facilities and the lack of U.S. regulations restricting the use of HFCs has delayed implementation in the U.S. However, there are other manufacturers currently selling refrigerators in the U.S. that use cyclopentane. Compared to other insulating foams, cyclopentane is competitively priced and relatively easy to produce. Like many gases, in its pure form, cyclopentane is a highly evaporative and flammable material. However once foamed, the unit is no more hazardous than a unit foamed with other blowing agents. As with any of our manufacturing processes, we’ve integrated a wide variety of redundant engineering and operational safeguards. To learn more about cyclopentane, click here.

 Common questions about cyclopentane

Q: What is this new material being used in the foam insulation?
A: The new material is called cyclopentane, a highly evaporative gas that is used to apply the foam insulations in refrigeration units. 

Q: What is cyclopentane?
A: Cyclopentane is a blowing agent for the polyurethane foams that are used to insulate refrigerators and freezers. 

Q: What are the benefits of using cyclopentane instead of other materials?
A: From an environmental perspective, unlike some other chemicals used to insulate refrigerators, cyclopentane does not contain hydro-fluorocarbons (HFCs). Using cyclopentane results in significant reductions in equivalent CO2 emissions. 

Q: What foam-blowing agents are most commonly used in the U.S.? How is cyclopentane different?
A: The most common foam-blowing agents in the U.S. right now are R134a and R245fa. These two industry-standard insulations can have a global warming potential (GWP) as high as 1300 (134a) and 950 (245a). Comparatively, the foam-blowing agent cyclopentane has a GWP of approximately 10. When it comes to GWPs, the lower the number is, the less adverse impact on the environment, so cyclopentane is clearly a better choice. 

Q: Are there significant insulating advantages, as well?
A: Yes, cyclopentane is approximately 4 percent more efficient than the R134a foam we currently use in most of our products. 

Q: Do other refrigerators available in the U.S. market use cyclopentane?
A: There are other manufacturers currently selling refrigerators in the U.S. that use cyclopentane. 

Q: Why hasn’t cyclopentane caught on in the United States?
A: It has been very popular as a blowing agent in Europe since the early 1990s, but the cost of retrofitting existing production facilities and the lack of U.S. regulations restricting the use of HFC’s has delayed implementation in the U.S. 

Q: Is it more expensive than other insulating materials?
A: It is competitively priced and relatively easy to produce. 

Q: Is it dangerous?
A: Like many gases, in its pure form, cyclopentane is a highly evaporative and flammable material. However once foamed, the unit is no more hazardous than a unit foamed with other blowing agents. As with any of our manufacturing processes, we’ve integrated a wide variety of redundant engineering and operational safeguards.

What is the difference between EPS fire resistance levels A, B, and B1?

The difference between EPS fire resistance grades A, B, and B1:

  1. Fire resistance coefficient: Class A is non combustible; Level B is further divided into three levels, with B1, B2, and B3 having different levels of combustion.
  2. Flammability: Class A has zero flammability;, B1 is flame retardant, B2 is flammable, and B3 is flammable.
    At present, the common A-grade products in the market include phenolic aldehyde, rock wool, insulation mortar, foam ceramics, foam glass, and foam concrete. At present, the most advantageous A-grade material is foamed concrete, also known as foamed cement.
    EPS polystyrene board itself is a flammable material, so it is not a fireproof material in terms of fire rating. So it’s not at all A-level or B1 level. The fire resistance rating of polystyrene boards on the market is only B2 (flammable) and B3 (flammable).
    Extended Information:
    EPS physical and mechanical properties:
  3. Density
    The density of EPS is determined by the expansion ratio of polystyrene particles during the forming stage, which is generally between 10 and 45kg/m3. As EPS used in engineering, its apparent density is generally between 15 and 30kg/m3.
    At present, the density of EPS used as lightweight filling material in road engineering is 20kg/m3, which is 1% to 2% of that of ordinary road filling material. Density is an important indicator of EPS, and its mechanical properties are almost directly proportional to its density.
  4. Deformation characteristics
    When the confining pressure exceeds 60KPa, the yield strength significantly decreases, which is clearly different from the variation law of the soil. When axial strain ε When a ≤ 5%, regardless of the confining pressure, the volumetric strain ε V is close to axial strain ε a. The lateral deformation of EPS is small, which means the Poisson’s ratio is small.
    To minimize post construction settlement, after laying the EPS material layer, fill 1.2m of soil on it for preloading. The average compressive settlement of the EPS material layer is 32mm, and it can be calculated that the elastic modulus of EPS is 2.4MPa, and the EPS material is still in the elastic deformation stage.
  5. Self-reliance
    The self-sustaining nature of EPS is very beneficial for the stability of high slopes. Due to the small lateral pressure generated by the vertical compression of EPS, the use of EPS as filling material for the roadbed at the bridge head can greatly reduce the soil pressure behind the abutment, which is very beneficial for the stability of the abutment.
    The friction coefficient f between EPS block and sand is 0.58 (dense)~0.46 (loose) for dry sand and 0.52 (dense)~0.25 (loose) for wet sand; The range of f between EPS blocks is between 0.6 and 0.7.
  6. Water and temperature characteristics
    The closed cavity structure of EPS determines its good insulation performance. Its biggest characteristic when used as insulation material is its extremely low thermal conductivity, with various specifications of EPS boards having thermal conductivity ranging from 0.024W/m.K to 0.041W/m.K. EPS is a thermoplastic resin that should be used below 70 ℃ to avoid thermal deformation and strength reduction.
    Simultaneously utilizing this feature, electric heating wire processing can be used. Flame retardants can be added in production to form flame retardant EPS. Flame retardant EPS extinguishes itself within 3 seconds after leaving the ignition source. Due to the much lower bulk density of EPS compared to soil, the 1% to 10% increase in bulk density caused by water absorption can have negligible impact on engineering.
  7. Durability
    EPS has stable chemical properties in water and soil, and cannot be decomposed by microorganisms; The cavity structure of EPS also makes water infiltration extremely slow; If exposed to ultraviolet radiation for a long time, the surface of EPS will change from white to yellow, and the material will appear brittle to some extent; EPS has stable properties in most solvents, but can be dissolved in organic solvents such as gasoline, diesel, kerosene, toluene, acetone, etc. This indicates that EPS fillers require a good protective layer.

    Reference Source: JUNYUAN PETROLEUM GROUP – EPS Blowing Agent Department (Folystyrene Foam)

Expandable polystyrene (EPS)

Revolutionary patented polystyrene production method

Expandable polystyrene (EPS) consists of polystyrene micro-pellets or beads containing a blowing agent and other additives for foaming. We have developed a continuous production process in which the blowing agent is directly injected into the melt, combined with subsequent underwater pelletization.

Commercial EPS is manufactured with the addition of a blowing agent, typically a chlorinated hydrocarbon or a low-boiling petroleum-derived agent with the presence of pentane. These substances are highly flammable; by reducing the amount of flame retardant due to the addition of gypsum, they ignited during the flame propagation test, increasing the burn rate of the GPS.

Main benefits

  • The patented EPS process is economical, compact, and easy to operate
  • Continuous process for consistent product quality
  • Dispersing a wide range of additives and pigments is possible
  • Minimized waste production
  • Reduction of wastewater and process water
  • Recycling possibility for waste EPS pellets/beads/foam
  • Process allows developing innovative applications

Main applications

  • Expandable Polystyrene

EPS Panel

The self-extinguishing, fire-retardant EPS Panel foam is manufactured from 100% virgin bead and oven-cured after manufacture to ensure the resulting blocks are completely dry and free from all residual pentane.

EPS Panel is a lightweight, CFC-free, non-brittle, closed cell insulator with more consistent thermal performance over time. It has a high dimensional stability and low water vapor transmission.

A special chemical coated to the Expanded Polystyrene beads (raw material) distinguished it from standard/common EPS Panel. Fire-Retardant EPS Panel is a self-extinguishing, non-combustible material.

Fire-retardant EPS Panel with a density of 15 kg/m3 is used for clean rooms, food processing facilities and modular buildings, while the 20 kg/m3 is used for industrial and commercial cold storage.

Core

Width (cover mm)
Thickness (mm)
Length
Exterior Facing Skin
Internal Facing Skin
Standard Colors
Joint System
Finishes
Type of SkinEPS
(Expanded Polystyrene)
1,160
50, 75, 100, 125, 150, 200, 250
Up to 12 meters
0.5mm, 0.6mm G300 CRP Steel
0.5mm, 0.6mm G300 CRP Steel
Off White
Slip Joint
Plain, Ribbed, Diamond
Anti Bacterial (AB)
Food Grade (FG)
Xterior Roof and Wall (XRW)

Features and Advantages

  • Fire retardant
  • Meets safety requirements
  • Energy saving
  • Longer lifetime
  • Resistant to termites and rodents
  • Customized design
  • Easy to install saving cost of installation time
  • High performance on insulated panel

Development Trend of Refrigerants

Development Trend of R601 Refrigerants

Product Description: n-Pentane; Pentane; Normal Pentane

GAS No.: 109-66-0

Packaging Specification: ISO-TANK

R601 Refrigerant Introduction

R601 refrigerant, pentane and n-pentane in Chinese, is a colorless liquid with faint mint fragrance. n-Pentane R601 is slightly soluble in water, and soluble in ethanol, ether, acetone, benzene, chloroform and other organic solvents, with a melting point of – 129.7 ℃ and a boiling point of 36.1 ℃.

R601 Refrigerant Application

R601 is mainly used for molecular sieve desorption, replacing Freon as foaming agent, as solvent, manufacturing artificial ice, agent, and synthesizing amyl alcohol.



Storage and Transportation

R601 refrigerant cylinder is a pressurized container, which should be stored away from fire, heat source and direct sunlight. It is usually stored in a cool, dry and ventilated warehouse; The steel cylinder, valve and other accessories shall be handled with care to prevent damage.

It is a general trend to use green and environment-friendly refrigerants. Green and environment-friendly refrigerants can be synthetic or natural. Although synthetic environment-friendly refrigerants will not damage ozone, natural refrigerants are the most ideal choice for the sustainable development of the earth’s ecology.

The history of refrigeration technology is actually the history of refrigerant development process. In the early days, people used the evaporation effect of storing natural ice and water and some other methods to refrigeration. In the 1930s, Perkins invented the vapor compression refrigeration cycle, and mankind ushered in the development period of refrigeration technology. The invention, renewal and replacement of refrigerants throughout the entire process. At present, according to the development requirements of the new era, refrigerants will face new challenges. At present, the development of refrigerant is divided into four stages, and the characteristics of each stage are shown in the left figure.

In general, the development trend of refrigerant should meet the requirements of sustainable development of ecological environment and promote its further development. According to the core requirements of coordination between economic development, resource protection and ecological environment protection in sustainable development, there are two development directions of refrigerant:

The first is environmental protection. It is a general trend to use green refrigerants. Green refrigerants can be synthetic or natural. Although synthetic environmental refrigerants will not damage ozone, natural refrigerants are the most ideal choice for the sustainable development of the earth’s ecology.

The second is energy conservation. With the improvement of people’s living standards, refrigeration, air conditioning and other equipment are becoming more and more popular, and at the same time, a large amount of energy consumed by them is also attracting more and more attention. This summer, 18 provinces and cities in China experienced a shortage of electricity. A survey by the China Electricity Regulatory Commission showed that the intensification of the contradiction between supply and demand caused a shortage of electricity this summer, of which the rapid growth of air-conditioning refrigeration load is a factor that cannot be ignored. Therefore, in addition to improving refrigeration technology, we can also start from refrigerants. It is also a development direction to reduce the energy consumption of refrigeration and air-conditioning equipment by developing new energy-saving refrigerants.

To sum up, the development of refrigerants is closely related to environmental protection and the sustainable development of the earth’s ecological environment. The development trend of refrigerants reflects the requirements of sustainable development of the environment.

Pentane Blend Market Price on September 09, 2022

The price of Pentanes in China has fluctuated greatly in the recent month. After a period of decline, it has been rising in the recent month, with a weekly price increase of about 100 CNY per ton The prices of n-/Isopentane and cyclo-/Isopentane also maintained an upward trend. Junyuan Petroleum Group believes that Pentane prices are now at a relatively low point this year, and manufacturers in urgent need of raw materials can start purchasing. In addition, the sea freight to all parts of the world has been reduced by half, compared with the same period last year.

Pentane products are widely used as blowing agent, solvent and chemical raw materials. At present, Junyuan Petroleum Group is the largest manufacturer of high-purity Isopentane, n-Pentane, Cyclopentane and Pentane Blends/Blowing Agents in the Chinese market, with an annual output of 800,000 tons.


Pentane Blend (Blowing Agent) Market Price on September 09, 2022

Product

City

Low End Price

High End Price

Mainstream Price

Rise and Fall

Incoterms

Remarks

n-/Isopentane

Dongying

7900

8050

7950

0

EXW

Cyclo/Isopentane

Dongying

7900

8050

7950

0

EXW

Remarks:
1. The price in this list is the price including tax in spot exchange, and the unit is CNY / ton;
2. Release time: before 17:00 on working days, for reference only;
3. The rise and fall are compared with the closing price of the previous working day.



n-/Isopentane Refrigeration Foaming

Refrigerant is the working medium of refrigeration, also known as refrigerant, snow. In the refrigeration system, it is vaporized by absorbing energy from the cooling medium in the evaporator, and transfers heat to air and water in the condenser to condense. The increase in the consumption of refrigerants in China also drives the demand for refrigerants. Another point is that the state promotes fluorite as a strategic resource for protective development. In combination with these reasons, the price of refrigerants gradually rises.

At present, there are more than 80 kinds of substances used as refrigerants, including ammonia, freon-12, Freon-22, R-134a, r-404a, R-410A, azeotropic and hydrocarbon refrigerants. Previously, with regard to the impact on the ozone layer, the production of CFC substances such as R11, R12, R113, R114, r115, R502 and R22 was restricted.

In the early days, most of the refrigerants were flammable or toxic, and some accidents often occurred due to excessive pressure. The history of the development of isobutane R600a refrigerant appeared in the middle of the 19th century. It was a vapor compression system using ether as the refrigerant. Carbon dioxide (CO2) and ammonia (NH3) were first used as refrigerants in 1866 and 1873, respectively. Other chemicals include chemical cyanide (petroleum ether and naphtha), sulfur dioxide (r-764) and methyl ether, which have been used as refrigerants for vapor compression. Its application is limited to industrial processes. Most foods are still preserved with ice cubes collected in winter or prepared industrially.

R290 refrigerant, propane refrigerant, is a hydrocarbon refrigerant, which has no damage to the ozone layer and has a very small greenhouse effect. It is actually an environmental protection refrigerant today. From the perspective of environmental protection, almost all countries in the world have no restrictions on the use of R290 refrigerant in the initial installation of new refrigeration equipment and after-sales maintenance. The product is mainly used to replace R22 and R502 refrigerants in low-temperature refrigeration equipment; Because R290 is flammable, it is usually only used in low-temperature refrigeration equipment with less liquid filling, or as a component of low-temperature mixed refrigerant; R290 is compatible with conventional lubricants. The R290 refrigerant steel cylinder for storage and transportation is a pressurized container, which is flammable and explosive. During storage, it should be kept away from kindling and heat sources and avoid direct sunlight exposure. It is usually stored in a cool, dry and ventilated warehouse; During handling, it shall be loaded and unloaded with care to prevent damage to steel cylinders, valves and other accessories. Matching refrigeration oil for the refrigeration engine oil matched with R290 refrigerant, it should follow the recommendations of the manufacturers of refrigeration compressors and refrigeration (air conditioning) equipment, or determine to use the refrigerator lubricating oil with the same design requirements according to the specific conditions of the refrigeration compressors and refrigeration equipment, that is, select the equivalent refrigeration engine oil.

The refrigerant in the refrigerator is added with fluorine in a fixed amount. Use a fixed amount dispenser to add fluorine according to the marked amount. When adding fluorine, feel whether the return pipe is cool by hand. If the return pipe is cold or slightly dewy, the evaporator can be basically covered with frost. When filling, first add less fluorine than the original amount and let it run. When the evaporator is full of frost, finally add it to the return pipe only to condense dew. Generally speaking, the steps of fluorinating the refrigerator are very simple. Vacuumize the refrigerator, pump out the air inside, and then add fluorine. Then seal the refrigerator.

The use of new environmentally friendly refrigerants does not destroy the ozone layer, and the refrigeration efficiency is higher than before. The use of new hydrocarbon refrigerants has also begun internationally, which fully meets the international standards for energy conservation, environmental protection and emission reduction. It is the ideal refrigerant in the world at present.

Pentane is the most common expansion agent in EPS production

Basic knowledge of expandable polystyrene (EPS)

Expandable polystyrene (EPS) is produced in a suspension process by adding a blowing agent, usually pentane, which causes resin to foam during moulding. The process may be performed as a single step or a two step process. The two step process passes the blowing agent though the polystyrene beads during, or after, polymerisation. Expanded polystyrene (EPS) is produced from a mixture of about 90-95% polystyrene and 5-10% gaseous blowing agent, most commonly pentane. The solid plastic is expanded using steam and is injected in to an aluminum tool under high pressure. Whether white or coloured, EPS starts life the size of a grain of salt. Polystyrene is produced from the crude oil refinery product styrene. For manufacturing expanded polystyrene, the polystyrene beads are impregnated with the foaming agent pentane. Polystyrene granulate is prefoamed at temperatures above 90°C.

Expanded polystyrene (EPS) is a light polymer made of the following materials:

  • Styrene – forming honeycomb structure
  • Pentane – used as blowing agent

Styrene and pentane are both hydrocarbons obtained from oil and natural gas by-products. EPS is composed of 98% air. Styrene, together with pentane, water and other chemicals, is converted into tiny EPS (expandable polystyrene) beads through a mixing reactor. The beads are then dried, sieved and finally coated.

In 1950, BASF developed EPS, which was widely used in the construction field because of its excellent thermal insulation performance. Later, it was widely used in packaging because of its strong impact resistance.

EPS raw material beads have been mixed with blowing agent when they are produced, generally 4-7% pentane. High temperature steam foaming molding is used in the mold, and up to 98% of the finished products are air. The beads can be divided into flame retardant and non flame retardant, and can also be divided into large, medium and small according to the radius.

  • Production process: pre foaming → curing → molding
  • Pre foaming: use 80-100 ℃ steam to heat the raw material to increase the bead size by 40-50 times.
  • Ripening: the prepared beads are dried in the silo to balance the internal pressure. The beads will have greater mechanical elasticity.
  • Molding: the pre sent and dried beads are transferred to the mold, and the steam is added again to make the beads stick together to generate the finished product.
  • Characteristics: low thermal conductivity, low density, high mechanical property, low water absorption, easy operation and installation, aging resistance, sound insulation and buoyancy.

The closed cell structure can cushion the impact by changing and restoring the deformation. The thermal conductivity is 0.033-0.043w / (m · K). Long term exposure to ultraviolet light will affect performance. It has no nutritional value, will not be eroded by mold, and will not decompose any water-soluble substance that pollutes groundwater.

A study by the packaging School of Michigan State University found that when fruits and vegetables are packaged with EPS, the carbon dioxide released by them will be retained, delaying maturation, and the content of vitamin C can be more effectively maintained.

Challenges facing the industry:

  • 1. Fire. Flame retardant is usually added to improve the flame retardancy of EPS.
  • 2. Recycling. Physical recovery method: the recovered compacted volume becomes 1 / 40 of the original, which is convenient for transportation and re production. The cost of the dissolution method is high. Used for incineration and energy recovery. EPS is not easy to degrade and can be used for landfill.

Price Trend Chart of n-Pentane in China Market

In the recent month, the price of n-Pentane in the Chinese market generally showed an upward trend. From July 28 to August 3, the price remained at about 6,900 yuan, and on August 5, it rose to about 7,000 yuan. Until August 17, the product price remained at this level. In late August, the price continued to rise, and until August 26, the price remained at about 7,100 yuan.

n-Pentane is an organic compound with the chemical formula of C5H12. It is mainly used as a solvent, a reference liquid for gas chromatography, and an anesthetic. It can also be used to make artificial ice, anesthetics, and synthesize pentanol and Isopentane.

Product Purity Grade (% wt) CAS No. Applications
n-Pentane EPS Grade (95%) 109-66-0 Pentane blowing agent 
General Grade (95%) 109-66-0 Thermacol
General Grade (95%) 109-66-0 Rigid foams for thermal insulation panels in the construction sector
PU Grade (95%) 109-66-0 Sandwich Panel
Polymer Grade (95%) 109-66-0 LLDPE & HDPE
Pharma Grade (99%) 109-66-0 Linear Alkayl Benzene
LAB Grade (99%) 109-66-0 Surfactant

Pentane Blends

Pentane Blends/Blowing Agents

Pentane is the most common expansion agent in EPS production. Low concentration of pentane can be trapped during production, inside the closed cells of EPS. By the end of the production cycle, EPS products may still contain 1-2% of Pentane by weight (Dongying Liangxin Petrochemical Technology Development Limited Company, a subsidiary of Junyuan Petroleum Group) . At this concentration, pentane can build up in the air around EPS at concentrations way above the flammability point or exceed the occupational exposure limit for pentane.

S/N Item Specifications
1 Appearance Colorless transparent liquid, no turbidity
2 Mechanical Impurities Not Found
3 Sulfur(ug/ml) <5
4 Blend of n-Pentane/Isopentane(wt%) 70:30,40:60, 50:50, 80:20, 85:15
Blend of Cyclopentane/Isopentane(wt%) 70:30
5 n-Pentane, Isopentane(wt%) ≥99
Cyclopentane, Isopentane (wt%) ≥99
6 Content Difference(wt%) ±2
7 C5﹣(wt%) ≤1
8 C6+(wt%) ≤0.5
9 Total Olefins(wt%) ≤0.1
Pentane Blend and Blowing Agent

Blend of n-Pentane/Isopentane(wt%) 70:30,40:60, 50:50, 80:20, 85:15 Blend of Cyclopentane/Isopentane(wt%) 70:30

Physical and chemical properties of pentane
Pentane isomers that are used as expanding agents for EPS

Isomer  Formula   Boiling point
n-Pentane CH3 – ( CH2 )3 – CH3 36.1 °C
Isopentane CH3 – CH( CH3 ) – CH2 – CH3 28.0 °C
Cyclopentane  CH2CH2CH2CH2CH2 49.0 °C

A company has been investigating a range of new blowing agents, previously identified as the AFA series (1). Designed for most PUR applications including appliances, pour-in-place (PiP), spray, and polyisocyanurate (PIR) bunstock/boardstock, these molecules possess very low global warming potential and negligible ozone depletion.
Among them, Forane® FBA 1233zd, which is a liquid under ambient conditions, is a potential candidate for replacement of HFCs 245fa and 365mfc and pentanes. Table below summarizes the properties of Forane® FBA 1233zd and references other blowing agents currently in use such as cyclopentane (cC5), isopentane (iC5), normal pentane (nC5), HFC 245fa, HFC 365mfc and HCFC 141b.

Pentane as expanding agent for EPS

Ever since EPS was developed, predominantly, almost exclusively, pentane has been used as its expanding agent (with approx. 6 %, based on EPS weight). Mainly n-pentane was, and still is, used. Various EPS raw material manufacturers add some Iso-pentane and recently some also add Cyclopentane. All these pentane isomers cause the same reactions in air (Ozone formation) and therefore are treated all as VOCs by environmental authorities.

Applications:

  • EPS Blowing Agent
  • Electronic Cleaning
  • Chemical Solvent
  • Aerosol Propellant
  • Others

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