Category TBPS

Advanced Sulfiding Solutions for a Cleaner & Greener Energy Transition 

The Green Energy & Hydrogen Summit 2025, held alongside the Oil, Gas & Power World Expo 2025 in Mumbai, brought together industry leaders to discuss India’s transition toward a net-zero future. Among the key speakers, Pawan Mehndiratta, SBU Head – Green Hydrogen at Thermax, highlighted the company’s role in advancing sustainable energy solutions.

Key Takeaways from the Discussion on Green Hydrogen & Derivatives:

✅ Green energy transition is a natural step for Thermax, leveraging its expertise in renewable energy and fuel cells.

✅ The company’s partnership with Ceres Power for SOEC Electrolysers will enhance efficiency by integrating waste heat recovery technology.

✅ Policy developments, cost economics, and industry incentives are essential for accelerating the green transition.

✅ Large-scale adoption of green hydrogen depends on technological advancements and competitive pricing.

The Role of Advanced Sulfiding Agents in a Cleaner Energy Future

As industries move toward sustainable energy solutions, achieving cleaner and more efficient operations becomes crucial. In the ethylene industry, catalyst performance plays a vital role in optimizing energy use and reducing emissions. This is where advanced sulfiding agents such as Di-tert-Butyl Polysulfide (DTBPS) and Tertiary Butyl Polysulfide (TBPS) make a significant impact.

These compounds are essential for activating and stabilizing hydrotreating catalysts, ensuring optimal performance in steam crackers and hydrogenation processes. By enhancing catalyst efficiency and minimizing sulfur-related emissions, they contribute to cleaner production processes, aligning with global net-zero and sustainability goals.

Technology, Policy & Innovation – A Synergistic Approach

The acceleration of green hydrogen adoption and broader energy transition requires a combination of technological advancements, regulatory support, and economic feasibility. As Thermax drives innovation in green hydrogen, solutions like DTBPS and TBPS play an integral role in making traditional industrial processes more sustainable and environmentally friendly.

Excited to see how the industry continues to evolve toward a greener and more efficient future! 

#GreenHydrogen #EnergyTransition #Sustainability #EthyleneIndustry #DTBPS #TBPS #CleanEnergy #NetZero #HydrogenEconomy

Tertiary-Butyl Polysulfide (TBPS) and Di-tert-Butyl Polysulfide (DTBPS) are both widely used sulfur-containing compounds in industrial applications

Boost Your Catalysis with DTBPS or TBPS

The Ultimate Polysulfide Solution for Catalyst Sulfidation

In the world of petroleum refining and petrochemicals, catalyst performance is paramount. To ensure maximum efficiency, stability, and longevity, catalyst activation through sulfidation is crucial. Enter DTBPS (di-tert-butyl polysulfide) or TBPS, an innovative polysulfide compound that is revolutionizing the way catalysts are treated before use.

DTBPS or TBPS is a specialized agent designed to provide the most effective and controlled sulfidation process for catalytic systems. It ensures optimal performance in key refining processes such as hydrocracking, catalytic cracking, and hydrotreating. By forming a protective sulfur layer on the catalyst surface, DTBPS or TBPS significantly enhances the catalyst’s activity and resistance to deactivation, resulting in longer operational life and higher throughput.

One of the most compelling reasons to incorporate DTBPS or TBPS into your catalyst preparation process is its ability to create a stable sulfurized surface quickly and efficiently. This not only maximizes catalyst efficiency but also minimizes the risk of catalyst poisoning from impurities that may be present in feedstock. With DTBPS or TBPS, refineries are able to streamline their operations, improve the quality of refined products, and optimize overall plant performance.

Furthermore, DTBPS or TBPS’s versatile and high-performance nature makes it suitable for a wide range of refining and petrochemical processes. Whether you’re dealing with heavy crude oil or more complex feedstocks, this polysulfide is a key tool in ensuring that your catalytic systems perform at their peak.

In today’s competitive energy market, operational efficiency is key. By choosing DTBPS or TBPS, you are ensuring that your catalysts perform at their highest capacity, reduce downtime, and increase product yields, all while protecting the environment by minimizing emissions and waste.

Upgrade your catalyst sulfidation process with DTBPS or TBPS and see the difference in your refining operations. With DTBPS or TBPS, expect enhanced catalyst stability, longer service life, and superior overall performance.

#CatalystSulfidation #RefiningEfficiency #DTBPS #TBPS #PolysulfideInnovation #EnergyOptimization #Hydrocracking #CatalyticCracking #RefiningExcellence #PetrochemicalPerformance

dtbps di-tert-butyl polysulfide chemical structure

FAQ: How to Represent the Chemical Structure of DTBPS (Di-tert-Butyl Polysulfide)?

Summary

Di-tert-Butyl Polysulfide (DTBPS) is an organic polysulfide compound consisting of two tert-butyl (-C(CH₃)₃) groups connected by a polysulfide chain (-Sₓ-). The number of sulfur atoms (x) can vary, typically x ≥ 2. This FAQ provides textual representations of its chemical structure and suggests tools for visualization.

Keywords

• Di-tert-Butyl Polysulfide (DTBPS)

• Polysulfide (-Sₓ-)

• tert-Butyl (-C(CH₃)₃) Group

• Chemical Structure Representation

• Molecular Drawing Tools

Q: What is DTBPS (Di-tert-Butyl Polysulfide)?

A: DTBPS is an organic polysulfide with the general formula (C₄H₉)₂Sₓ, where x represents the number of sulfur atoms. It consists of two tert-butyl (-C(CH₃)₃) groups connected by a polysulfide (-Sₓ-) chain. The sulfur chain length can vary depending on the specific compound variant.

Q: How can the chemical structure of DTBPS be represented in text?

A: The molecular structure of DTBPS can be written as follows: (CH3)3C-Sx-C(CH3)3

Where Sₓ represents a polysulfide chain (S₂, S₃, S₄, etc.).

For example, if x = 3 (trisulfide), the structure can be represented as: CH3 | CH3—C—S—S—S—C—CH3 | CH3

Q: How can I visualize the chemical structure of DTBPS?

A: You can use the following molecular drawing tools:

• Software:

• ChemDraw or ChemSketch (professional chemical drawing software)

• Online Tools:

PubChem Sketcher

MolView

If you need a specific DTBPS variant (e.g., with a different number of sulfur atoms), adjust the Sₓ chain length accordingly.

A worker in red safety gear and a white helmet inspects chemical storage containers at a DTBPS application site in a refinery.

Safer and More Efficient Sulfiding: Introducing Di-tert-butyl Polysulfide (DTBPS)

Transforming Catalyst Activation in Refineries with Safer Alternatives

Abstract: Sulfiding, the process of activating hydroprocessing catalysts in refineries, traditionally relied on dimethyl disulfide (DMDS). While effective, DMDS presents safety, handling, and environmental challenges. Di-tert-butyl polysulfide (DTBPS) emerges as a superior alternative, offering increased safety due to a higher flashpoint, a less offensive odor, nonregulated transportation, and reduced SOx emissions. Pilot studies confirm that DTBPS performs on par with DMDS while enabling quicker sulfiding at lower temperatures. Despite minor differences in sulfur content, DTBPS is endorsed by catalyst manufacturers as a safer, efficient, and environmentally favorable sulfiding agent.

Keywords: Sulfiding, hydroprocessing catalysts, DTBPS, DMDS, refinery safety, SOx emissions, catalyst activation.

This article explores the key factors in the sulfiding process of hydroprocessing catalysts and their impact on catalyst performance. By analyzing the types of sulfiding agents, sulfiding conditions (e.g., temperature, pressure, time), and catalyst support properties, effective strategies for optimizing the sulfiding process are proposed. The article highlights Di-tert-butyl Polysulfide (DTBPS) as a novel sulfiding agent, which offers superior safety, lower odor, and easier transportation and storage compared to the traditional Dimethyl Disulfide (DMDS). Laboratory and industrial-scale studies demonstrate that DTBPS performs equally to DMDS in terms of sulfiding efficiency and catalyst performance, while significantly reducing environmental risks and operational costs. The article concludes with future research directions, emphasizing the need for further advancements in sulfiding technology driven by both environmental and economic benefits.

Key Terms:

  • Hydroprocessing catalysts
  • Sulfiding process
  • Di-tert-butyl Polysulfide (DTBPS)
  • Dimethyl Disulfide (DMDS)
  • Catalyst performance
  • Optimization strategies
  • Industrial applications
  • Environmental technology

Main Content

1. Importance of the Sulfiding Process

Hydroprocessing catalysts are widely used in refineries for hydrotreating, hydrodesulfurization, and hydrocracking units. Initially, catalysts are in an inert/inactive state, with active metals in oxide form. Sulfiding activates the catalyst by reacting the active metals with hydrogen sulfide, which is typically generated in situ from sulfur in the feedstock or provided by a sulfiding agent.

2. Limitations of Traditional Sulfiding Agent DMDS

Dimethyl Disulfide (DMDS) has been widely used as a sulfiding agent for many years, but it has several drawbacks:

  • Safety Hazards: DMDS has a low flash point (16°C), posing fire risks during transportation, storage, and use.
  • Odor Issues: DMDS has a strong, unpleasant odor, which can be a nuisance to workers and surrounding communities.
  • Transportation Restrictions: Due to its low flash point, DMDS is subject to strict transportation regulations, potentially leading to additional demurrage charges.
  • Environmental Emissions: The methane produced during DMDS decomposition dilutes hydrogen in the recycle gas, increasing sulfur dioxide (SOₓ) emissions.

3. Advantages of the New Sulfiding Agent DTBPS

Di-tert-butyl Polysulfide (DTBPS) is a novel sulfiding agent with the following advantages:

  • Enhanced Safety: DTBPS has a high flash point (100°C), significantly reducing fire risks.
  • Low Odor: DTBPS has a mild, diesel-like odor, making it more tolerable for workers and communities.
  • Easier Transportation: Classified as non-hazardous, DTBPS offers greater flexibility in transportation and storage.
  • Environmental Benefits: The isobutane byproduct from DTBPS decomposition does not dilute hydrogen in the recycle gas, reducing SOₓ emissions.

4. Pilot-Plant and Industrial Applications

Pilot-plant studies confirmed that DTBPS performs equally to DMDS in terms of sulfiding efficiency and catalyst performance. DTBPS decomposes at a lower temperature (160°C) compared to DMDS (200°C), allowing sulfiding to begin at lower catalyst bed temperatures. This reduces the risk of catalyst damage due to high-temperature reduction and shortens the sulfiding process time.

5. Limitations of DTBPS

DTBPS has a slightly lower sulfur content (56%) compared to DMDS (68%), requiring a slightly higher dosage to achieve the same sulfiding effect. However, this drawback is outweighed by its safety, environmental benefits, and operational convenience.

6. Industry Acceptance and Future Outlook

DTBPS has been tested and approved by major catalyst manufacturers worldwide as a safe and efficient alternative to DMDS. As environmental regulations become stricter, DTBPS is expected to gain broader adoption in the refining industry.


Tables and Figures

  • Table 1: Comparison of DMDS and DTBPS Sulfiding Methods
  • DTBPS:
  • Low odor and high flashpoint (212°F/100°C): Safer to handle with reduced fire risk, allowing for nonregulated transport.
  • Low decomposition temperature (320°F/160°C): Provides a better safety margin for catalyst reduction.
  • Industry acceptance: Rapidly gaining global market share and approved by catalyst manufacturers.
  • Efficiency: Sulfiding process completes in 1-2 hours, which is faster than DMDS.
  • DMDS:
  • Strong odor: Described as “decaying cabbage,” making it unpleasant for workers and communities.
  • Low flashpoint (61°F/16°C): Requires Department of Transportation (DOT)-regulated transport and specialized handling.
  • Moderate decomposition temperature (392°F/200°C): Standard for current industry processes.
  • Industry standard: Widely recognized and approved, but the sulfiding process takes 18-36 hours, much longer compared to DTBPS.
  • Table 2: Comparison of Chemical and Physical Properties of DMDS and DTBPS
  • DTBPS is a safer and more efficient alternative to DMDS in catalyst sulfiding. It offers significant advantages such as:
  • Safety: A higher flashpoint and lower decomposition temperature make it safer and reduce the risks of fire.
  • Environmental Impact: DTBPS minimizes SOx emissions due to its byproduct (isobutane) and prevents hydrogen dilution in the recycle gas.
  • Convenience: Nonregulated transportation simplifies logistics, while low odor improves workplace conditions.
  • The trade-off for DTBPS is its lower sulfur content (56% vs. DMDS’s 68%), requiring slightly more volume to achieve equivalent sulfiding.
  • Pilot studies confirm DTBPS matches DMDS in catalytic activity and delivers added benefits like shorter sulfiding times (1-2 hours vs. 18-36 hours). Globally, catalyst manufacturers recognize DTBPS as an effective alternative. Overall, DTBPS’s properties make it the preferred choice for safer, faster, and environmentally favorable refinery operations.
  • Additional Insights: Hydrodesulfurization Efficiency of Catalysts Sulfided with DTBPS and DMDS
  • Hydrocarbon Byproducts:
    • DMDS produces methane as its hydrocarbon byproduct during sulfiding. This methane tends to accumulate in the recycle gas stream, diluting hydrogen and lowering the hydrogen partial pressure. This often requires gas purging and hydrogen makeup, leading to SOx emissions and wasted resources.
    • In contrast, DBPS generates isobutane, which exits with liquid hydrocarbons from the high-pressure separator. This prevents hydrogen dilution and reduces SOx emissions, making it a more environmentally responsible choice.
  • Operational Efficiency:
    • The lower decomposition temperature of DBPS (320°F/160°C) allows sulfiding to begin at a lower catalyst bed temperature, which reduces the risks associated with catalyst overheating (exotherms). This also shortens the sulfiding time, leading to cost savings by minimizing reactor downtime.
  • Global Adoption:
    • Catalyst manufacturers worldwide endorse DBPS as a viable alternative to DMDS. Its ease of use, safety advantages, and comparable effectiveness make it a promising choice for refiners aiming to optimize operations.
  • Minor Considerations:
    • The slightly lower sulfur content of DBPS (54% versus 68% for DMDS) requires a marginally higher volume of DBPS to achieve the same level of catalyst sulfiding. However, this minor inconvenience is outweighed by the safety, handling, and environmental benefits.
  • Conclusion:
  • DBPS stands out as a safer, more environmentally friendly, and efficient alternative to DMDS in the hydroprocessing catalyst sulfiding process. Its adoption reflects a move towards greener and more sustainable practices in the refining industry. While it does require a marginally larger dosage, the overall benefits—ranging from reduced SOx emissions to simplified handling—make it a compelling choice for modern refineries.

Conclusion

DTBPS, as a novel sulfiding agent, offers significant advantages in safety, environmental performance, and operational convenience, making it an ideal replacement for traditional DMDS. Despite its slightly lower sulfur content, its overall benefits make it the preferred choice for optimizing sulfiding processes in refineries.

Tertiary-Butyl Polysulfide (TBPS) and Di-tert-Butyl Polysulfide (DTBPS) are both widely used sulfur-containing compounds in industrial applications

TBPS/DTBPS: The Ultimate Catalyst Sulfiding Agent & Industrial Lubricant Additive

Unlocking the Power of Tertiary-Butyl Polysulfide for Refining, Lubrication, and Chemical Manufacturing

Abstract

Tertiary-Butyl Polysulfide (TBPS), also known as Di-tert-Butyl Polysulfide (DTBPS), is a high-performance chemical widely used in catalyst sulfiding, lubricant additives, and specialty chemical manufacturing. Its high sulfur content, stability, and unique chemical properties make it an essential compound for hydroprocessing catalysts, extreme-pressure lubricants, and industrial applications requiring sulfur-based additives. This article explores its chemical properties, industrial applications, advantages, and market trends, offering valuable insights into its growing importance across industries.

Keywords:

TBPS, DTBPS, Tertiary-Butyl Polysulfide, Di-tert-Butyl Polysulfide, catalyst sulfiding agent, industrial lubricants, hydroprocessing catalysts, extreme-pressure additives, sulfur compounds, petrochemical applications

1. Introduction

In the world of industrial chemistry, certain compounds stand out for their versatility and high performance. Tertiary-Butyl Polysulfide (TBPS), also known as Di-tert-Butyl Polysulfide (DTBPS), is one such compound. Renowned for its high sulfur content and stability, TBPS/DTBPS plays a critical role in oil refining, lubrication, and petrochemical processes.

As industries strive for cleaner fuels, more efficient refining processes, and high-performance lubricants, the demand for effective sulfiding agents and extreme-pressure additives continues to rise. This article breaks down the key properties, applications, and advantages of TBPS/DTBPS, demonstrating why it is an indispensable compound in modern industrial chemistry.

2. Chemical Composition and Properties

TBPS/DTBPS is a polysulfide compound featuring tertiary-butyl groups bonded to sulfur chains. The length of the sulfur chain determines the compound’s reactivity, stability, and industrial performance. The most common forms contain tetrasulfide (four sulfur atoms) or pentasulfide (five sulfur atoms) structures, making them highly effective in sulfiding applications.

Key Properties of TBPS/DTBPS:

• High sulfur content for effective sulfiding of industrial catalysts.

• Excellent thermal stability, allowing it to withstand high temperatures without decomposition.

• Moderate viscosity, making it easy to handle and mix in industrial processes.

• Low volatility, ensuring minimal loss due to evaporation in high-temperature applications.

• Good solubility in organic solvents, enhancing its application flexibility.

These characteristics make TBPS/DTBPS a reliable and efficient choice for industries requiring controlled sulfur release, high-temperature stability, and chemical reactivity.

3. Industrial Applications of TBPS/DTBPS

3.1 Catalyst Sulfiding in Oil Refining

One of the most significant applications of TBPS/DTBPS is in hydroprocessing catalyst sulfiding. In refining processes such as hydrodesulfurization (HDS), hydrocracking, and hydrotreating, catalysts must be converted from oxide form to sulfide form to become active.

TBPS/DTBPS serves as an efficient sulfiding agent, ensuring proper catalyst activation. It provides a controlled and gradual sulfur release, preventing catalyst deactivation and enhancing overall refining efficiency.

3.2 Extreme-Pressure Additive in Lubricants

TBPS/DTBPS is widely used in the lubricant industry as an extreme-pressure (EP) additive. In high-load, high-friction applications, such as industrial gear oils, metalworking fluids, and high-performance greases, it helps:

• Reduce friction and wear, extending equipment lifespan.

• Improve thermal and oxidative stability, ensuring lubricant performance under extreme conditions.

• Enhance load-carrying capacity, making it ideal for heavy-duty applications.

3.3 Specialty Chemical and Polymer Applications

Beyond refining and lubrication, TBPS/DTBPS is used as a chemical intermediate in producing sulfur-containing compounds, polymer additives, and rubber processing chemicals. Its ability to act as a sulfur donor makes it valuable in synthetic rubber production and polymer modification.

4. Advantages of TBPS/DTBPS Over Other Sulfiding Agents

1. Highly Effective Sulfur Source

• Provides a consistent and controlled release of sulfur, ensuring efficient catalyst activation.

• Reduces the risk of over-sulfiding or under-sulfiding, optimizing process efficiency.

2. Enhanced Stability and Handling

• More thermally stable than alternative sulfiding agents.

• Low volatility reduces handling risks and material loss.

3. Superior Lubrication Performance

• Functions as an extreme-pressure additive, protecting mechanical components under high-stress conditions.

• Reduces wear and tear, improving overall equipment reliability.

4. Versatile Industrial Applications

• Widely used in refining, petrochemicals, lubricants, and polymer industries.

• Compatible with various hydroprocessing catalysts and lubricant formulations.

5. Market Demand and Future Trends

As industries worldwide push for cleaner fuels, improved refining technologies, and advanced lubrication solutions, the demand for TBPS/DTBPS is expected to grow.

Market Insights:

• The rising adoption of hydroprocessing catalysts is driving the need for effective sulfiding agents.

• Stricter environmental regulations are encouraging refineries to optimize their processes using high-efficiency sulfiding compounds like TBPS/DTBPS.

• Advancements in extreme-pressure lubrication technology are promoting the use of sulfur-based additives to improve performance in demanding applications.

Given these trends, TBPS/DTBPS is poised to remain a key component in refining, lubrication, and specialty chemical industries for years to come.

6. Conclusion

TBPS/DTBPS stands out as a versatile and high-performance polysulfide compound with critical applications in catalyst sulfiding, lubrication, and chemical synthesis. Its high sulfur content, stability, and industrial efficiency make it an indispensable chemical in modern refining and manufacturing.

As global industries continue to evolve toward more efficient and sustainable solutions, the role of TBPS/DTBPS as a catalyst activator and lubricant enhancer will only grow stronger.

Would you like to explore how TBPS/DTBPS can optimize your industrial processes? Contact industry experts and suppliers today to learn more about its applications and benefits.

The Secret Power of Di-tert-butyl Polysulfide: A Game-Changer in Lubricants and Rubber Industry

By Junyuan Petroleum Group – The Leading Manufacturer of Di-tert-butyl Polysulfide in China

Abstract

Di-tert-butyl polysulfide (DTBPS) is revolutionizing the rubber and lubricant industries with its exceptional anti-wear, anti-oxidation, and vulcanization properties. As the world’s demand for high-performance additives grows, understanding the chemistry, synthesis, and industrial applications of DTBPS is crucial. In this article, we unveil how Junyuan Petroleum Group, China’s largest producer of DTBPS, is driving innovation and sustainability in this field.

Keywords:

Di-tert-butyl polysulfide, DTBPS, rubber vulcanization, lubricant additives, sulfur compounds, polysulfide synthesis, anti-wear agents, Junyuan Petroleum Group, industrial chemistry, sustainable lubricants

Why Is Di-tert-butyl Polysulfide (DTBPS) a Game-Changer?

Di-tert-butyl polysulfide (DTBPS) might not be a household name, but if you’ve ever used high-performance lubricants or durable rubber products, you’ve likely benefited from its powerful properties. This sulfur-rich compound plays a crucial role in enhancing the longevity and efficiency of industrial materials.

How Is DTBPS Synthesized?

The synthesis of DTBPS involves a simple yet highly efficient chemical reaction between tert-butyl mercaptan (t-BuSH) and sulfur (S) under alkaline conditions. The process can be broken down into three key steps:

1. Activation of tert-butyl mercaptan – In the presence of a base (such as sodium hydroxide), t-BuSH loses a proton, forming a reactive thiolate anion.

2. Reaction with sulfur – The thiolate anion reacts with elemental sulfur, leading to the formation of polysulfide chains.

3. Purification and Optimization – The final product is refined to achieve the desired sulfur chain length, optimizing its properties for industrial applications.

DTBPS in Lubricants: The Ultimate Anti-Wear Agent

Friction is the enemy of machinery. Traditional lubricants reduce wear to some extent, but with DTBPS-enhanced lubricants, the results are on another level. Here’s why:

• Anti-Wear Properties – DTBPS forms a protective sulfur film that significantly reduces metal-to-metal contact, preventing mechanical degradation.

• Thermal Stability – Unlike conventional sulfur additives, DTBPS remains effective even under extreme temperatures, making it ideal for aerospace, automotive, and heavy-duty industrial applications.

• Oxidation Resistance – It acts as a stabilizer, preventing oil from breaking down over time, which extends lubricant lifespan and reduces maintenance costs.

Revolutionizing the Rubber Industry with DTBPS

In the world of rubber manufacturing, sulfur cross-linking is essential for durability and elasticity. DTBPS is an advanced vulcanization agent that outperforms traditional sulfur additives. Benefits include:

• Faster Vulcanization – Speeds up the process, increasing production efficiency.

• Improved Flexibility – Creates stronger but more elastic rubber, ideal for tires, seals, and industrial belts.

• Better Aging Resistance – Rubber products last longer, reducing replacement frequency and waste.

Why Junyuan Petroleum Group Leads the DTBPS Market

Junyuan Petroleum Group has established itself as China’s largest and most reliable producer of Di-tert-butyl polysulfide. Here’s what sets us apart:

✅ Cutting-Edge Manufacturing – Advanced production facilities ensure the highest purity and efficiency of DTBPS.

✅ Global Supply Chain – We serve industries worldwide, from North America to Europe and Asia.

✅ Sustainability Commitment – Our green production processes minimize environmental impact, aligning with global sustainability goals.

✅ Custom Solutions – Tailored formulations meet the specific needs of lubricant and rubber manufacturers.

Final Thoughts: The Future of DTBPS

As industries push for more efficient, durable, and environmentally friendly solutions, DTBPS is becoming an essential component in advanced materials. With Junyuan Petroleum Group leading the charge, the future of lubricants and rubber products is brighter than ever.

Want to elevate your industrial performance? Contact us today to learn more about high-quality DTBPS solutions!

DTBPS: The Next-Generation Sulfurizing Agent for Cleaner and More Efficient Catalysis

Abstract

DTBPS (Di-tert-butyl Polysulfide) is an innovative sulfurizing agent widely used in hydroprocessing catalysts, ethylene cracking furnaces, and oil & gas desulfurization. As a safer and more environmentally friendly alternative to DMDS, DTBPS offers superior catalytic performance, lower odor emissions, and compliance with strict environmental regulations. With increasing demand for cleaner and more efficient sulfurizing agents, DTBPS is poised to become the preferred choice for the petrochemical and refining industries.

Keywords

DTBPS, sulfurizing agent, hydroprocessing catalyst, DMDS alternative, desulfurization, petrochemical industry, cleaner production, refinery technology, SZ-54, sustainable chemistry

Introduction: A Game-Changer in Sulfurization Technology

In the evolving landscape of the petrochemical industry, efficiency and environmental compliance are top priorities. DTBPS, a cutting-edge sulfurizing agent similar to Lubrizol’s SZ-54, has been gaining traction as a superior alternative to DMDS. With its high sulfur content, minimal odor, and non-hazardous classification, DTBPS is redefining sulfurization in hydroprocessing, ethylene cracking, and oilfield applications.

Why DTBPS? Key Advantages Over DMDS

1. Enhanced Catalytic Sulfurization Performance

DTBPS effectively sulfurizes hydroprocessing catalysts, achieving high activation levels necessary for producing ultra-low sulfur diesel (ULSD). Unlike DMDS, which generates methane during decomposition, DTBPS releases hydrogen sulfide (H₂S) and isobutane. This unique property helps maintain hydrogen partial pressure in the system, optimizing catalyst performance without the need for additional hydrogen supplementation.

2. Superior Environmental and Safety Profile

• Non-Hazardous Classification: Unlike DMDS, which is classified as a hazardous chemical requiring strict handling and transportation protocols, DTBPS is considered a non-hazardous substance, simplifying logistics and reducing compliance burdens.

• Low Odor Emissions: DTBPS significantly reduces unpleasant sulfur odors, improving workplace safety and minimizing environmental impact.

• Cleaner Combustion: When used as a coke inhibitor in ethylene cracking furnaces, DTBPS enhances efficiency while reducing emissions, aligning with global sustainability goals.

3. Growing Market Demand & Future Prospects

The increasing focus on environmental regulations and workplace safety is driving the transition from DMDS to DTBPS. Major petrochemical enterprises, including Sinopec and PetroChina, are actively exploring DTBPS as a next-generation sulfurizing solution. As regulatory bodies tighten restrictions on hazardous chemicals, the demand for DTBPS is expected to surge, positioning it as the future of clean sulfurization technology.

Conclusion: DTBPS – The Smart Choice for a Sustainable Future

DTBPS offers a compelling combination of high efficiency, environmental safety, and cost-effectiveness. As refineries and petrochemical plants seek cleaner and more sustainable solutions, DTBPS is set to become the industry standard for sulfurization processes. By adopting DTBPS, companies can enhance production efficiency, comply with stringent environmental regulations, and reduce operational risks—all while driving a cleaner energy future.

Contact Us

Junyuan Petroleum Group is committed to delivering high-performance sulfurizing agents for a cleaner and more efficient petrochemical industry. Contact us today to learn more about DTBPS and how it can optimize your refinery operations.

 Email: info@junyuanpetroleumgroup.com

 Website: https://junyuanpetroleumgroup.com

Dimethyl Disulfide (DMDS): Catalyst Sulfiding and Advantages

Dimethyl Disulfide (DMDS): Catalyst Sulfiding and Advantages

DTBPS chemical structure

What is DTBPS?

Di-tert-butyl Polysulfide (DTBPS)

DTBPS

Di-tert-butyl Polysulfide (DTBPS) is a specialized chemical compound primarily composed of tetra and penta sulfides. Unlike distilled materials, DTBPS boasts the highest sulfur content among manufactured polysulfides. It plays a crucial role in hydrotreating catalysts used in various industrial processes.

Common Namedi-tert-butyl polysulfide
CAS Number68937-96-2Molecular Weight188.20100
Density0.931g/cm3Boiling Point249.4ºC at 760 mmHg
Molecular FormulaC7H8O4SMelting PointN/A
MSDSN/AFlash Point85ºC (closedºCup)

Chemical & Physical Properties

Density0.931g/cm3
Boiling Point249.4ºC at 760 mmHg
Molecular FormulaC7H8O4S
Molecular Weight188.20100
Flash Point85ºC (closedºCup)
Exact Mass188.01400
PSA71.98000
LogP2.25740
Index of Refraction1.492

Properties and Applications

  • Composition: DTBPS is a blend primarily composed of tetra and penta sulfides.
  • Sulfur Content: It contains the highest sulfur content among manufactured polysulfides.
  • Usage: DTBPS finds application in the metalworking lubricant markets where it contributes to improving lubricity, reducing friction, and enhancing machining processes.

Other Polysulfides

In addition to DTBPS, other available polysulfides include:

  1. TNPS 537
  2. TDPS 532
  3. TDPS 320

While DTBPS is not directly related to Disinfection Byproducts (DBPs), it serves as a critical component in industrial catalysts. If you have any further questions or need more information, feel free to contact us! 🌟

dtbps di-tert-butyl polysulfide chemical structure

DTBPS – Safe and environmentally friendly vulcanizing agent is now on the market

Recently, Junyuan Petroleum Group has developed DTBPS (Di-tert-butyl Polysulfide) environmentally friendly and safe vulcanizing agent, which has the characteristics of no odor, low odor, high flash point, strong safety performance, and significant intrinsic safety characteristics. It has become an ideal green and reliable substitute for traditional dimethyl disulfide (DMDS) vulcanizing agent products.

It is understood that dimethyl disulfide is widely used as a pre sulfurization catalyst, sulfur injection for sulfur supplementation, and coking inhibitor for ethylene cracking in industry. Due to its good oil solubility and high sulfur content, it is widely used. However, it has strong irritancy, suffocating odor, toxicity, high risk factor, and high cost, which brings enormous pressure to the hydrogenation industry.

Based on this, Junyuan Petroleum Group has developed DTBPS (Di-tert-butyl Polysulfide) environmentally friendly and safe vulcanizing agent through collaborative innovation between industry, academia, and research. The flash point of this vulcanizing agent is over 100 ℃, which belongs to non flammable materials and greatly reduces potential production, transportation, and storage risks. Moreover, the decomposition temperature is low, and it can be injected into the system at around 160 ℃ to participate in the vulcanization reaction, increasing the activity of the catalyst and shortening the vulcanization time.

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