Tag Cyclopentane

Abstract: Rigid polyurethane foam (RPUF) is a widely used material for insulation, construction, and packaging applications. However, RPUF has some drawbacks, such as high flammability, low thermal stability, and environmental issues. To overcome these problems, researchers have explored the use of isoamyl and cyclopentane blends as blowing agents for RPUF. Blowing agents are substances that create gas bubbles in the foam, affecting its density, thermal conductivity, and mechanical properties. Isoamyl and cyclopentane are both hydrocarbons that have low ozone depletion potential (ODP) and global warming potential (GWP), making them more eco-friendly than conventional blowing agents. Moreover, they can improve the flame retardancy, thermal stability, and mechanical strength of RPUF. This article introduces the basic concepts of RPUF and blowing agents, and reviews the recent studies on the effects of isoamyl and cyclopentane blends on the properties and performance of RPUF.

Keywords: rigid polyurethane foam, blowing agent, isoamyl, cyclopentane, thermal conductivity, flame retardancy

Abstract:

Pipeline insulation is a technique that aims to reduce the heat loss and prevent the freezing of fluids in pipelines. Pipeline insulation is widely used in various industries, such as oil and gas, chemical, power, and water supply. Pipeline insulation can improve the energy efficiency, safety, and reliability of the pipeline system.

One of the main materials used for pipeline insulation is polyurethane foam (PUF), which is a type of thermosetting polymer that has excellent thermal and mechanical properties. PUF is formed by the reaction of polyol and isocyanate, which are mixed with a blowing agent that creates bubbles in the foam. The blowing agent determines the density, thermal conductivity, and environmental impact of the PUF.

Cyclopentane is a hydrocarbon that has been widely used as a blowing agent for PUF in recent years. Cyclopentane has many advantages over other blowing agents, such as low ozone depletion potential (ODP), low global warming potential (GWP), high solubility in polyol, and low cost. Cyclopentane can also enhance the flame retardancy and aging resistance of the PUF.

In this article, we will introduce the principle and process of pipeline insulation, the properties and advantages of cyclopentane as a blowing agent, and the challenges and solutions of using cyclopentane in pipeline insulation. We will also review the current status and future prospects of cyclopentane in pipeline insulation.

Keywords: pipeline insulation, polyurethane foam, cyclopentane, blowing agent, energy efficiency

Refrigeration and air conditioning systems are essential for preserving food, maintaining comfort, and enhancing productivity in various sectors. However, these systems also consume a lot of energy and contribute to greenhouse gas emissions. Therefore, finding ways to improve the efficiency and environmental impact of refrigeration and air conditioning systems is a crucial challenge for the industry.

One of the key factors that affects the performance and sustainability of refrigeration and air conditioning systems is the choice of insulation material. Insulation material is used to reduce the heat transfer between the refrigerated or conditioned space and the surrounding environment, thus minimizing the energy loss and the cooling load. The insulation material is usually made of polyurethane (PU) foam, which is formed by injecting a blowing agent into the liquid PU mixture. The blowing agent expands the PU mixture into a foam with tiny cells that trap air and provide thermal resistance.

The blowing agent is an important component of the insulation material, as it determines the thermal conductivity, density, and stability of the foam. Traditionally, chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) were used as blowing agents, but they were found to have a high ozone depletion potential (ODP) and global warming potential (GWP), meaning that they damage the ozone layer and contribute to climate change. Therefore, these substances were phased out by the Montreal Protocol and replaced by hydrofluorocarbons (HFCs), which have a lower ODP but still a high GWP.

In recent years, there has been a growing interest in using hydrocarbons as blowing agents, especially cyclopentane. Cyclopentane is a flammable organic compound with five carbon atoms arranged in a ring. It has several advantages over HFCs as a blowing agent, such as:

• Cyclopentane has a zero ODP and a negligible GWP, making it an environmentally friendly alternative to HFCs.
• Cyclopentane has a lower thermal conductivity than HFCs, resulting in a higher insulation value and a lower energy consumption for the refrigeration and air conditioning systems.
• Cyclopentane has a lower density than HFCs, allowing for a thinner insulation layer and a larger usable volume for the refrigerated or conditioned space.
• Cyclopentane has a higher stability than HFCs, reducing the aging and degradation of the foam over time.

Cyclopentane is widely used as a blowing agent for refrigerators and freezers, as it can improve the energy efficiency, CO2 reduction, and cost savings of these appliances²³⁵. Cyclopentane can also be used for other refrigeration and air conditioning applications, such as cold storage rooms, refrigerated trucks, and air conditioners¹⁴. However, the use of cyclopentane also poses some challenges, such as the flammability and toxicity of the substance, which require special safety measures and regulations during the production, transportation, and installation of the insulation material.

In conclusion, cyclopentane is a promising blowing agent for refrigeration and air conditioning systems, as it can enhance the performance and sustainability of these systems. Cyclopentane can reduce the energy consumption, greenhouse gas emissions, and costs of refrigeration and air conditioning systems, while increasing the usable volume and durability of the insulation material. Cyclopentane can also contribute to the protection of the ozone layer and the mitigation of climate change, as it has a zero ODP and a negligible GWP. Therefore, cyclopentane is a breath of fresh air for the refrigeration and air conditioning industry..

Polyurethane foam is a versatile material that is widely used in various applications, such as insulation, cushioning, packaging, and furniture. Polyurethane foam is made by reacting polyols (alcohol-based compounds) with isocyanates (organic compounds that contain nitrogen and carbon) in the presence of a catalyst and a blowing agent. The blowing agent is a substance that creates bubbles in the mixture, forming a cellular structure in the foam.

Cyclopentane is a type of hydrocarbon that has a ring of five carbon atoms. Cyclopentane can be used as a blowing agent for polyurethane foam, because it has a low boiling point (49°C) and a high vapor pressure (0.5 MPa at 25°C). This means that cyclopentane can easily evaporate and expand when heated, creating gas bubbles in the polyurethane mixture. Cyclopentane also has some advantages over other blowing agents, such as being non-flammable, non-toxic, and environmentally friendly.

The synthesis of polyurethane foam from cyclopentane can be summarized as follows:

1. A polyol, an isocyanate, a catalyst, and a small amount of cyclopentane are mixed together in a container at room temperature.
2. The mixture is transferred to a mold or a spray gun, where it is heated to about 60°C. The heat causes the polyol and the isocyanate to react, forming a polymer network. At the same time, the cyclopentane vaporizes and expands, creating bubbles in the polymer network.
3. The foam solidifies and cools down, forming a rigid or flexible polyurethane foam, depending on the type and ratio of the ingredients used.

Polyurethane foam made from cyclopentane has good thermal insulation, mechanical strength, and dimensional stability. It can be used for various purposes, such as refrigerators, water heaters, building walls, mattresses, and car seats.

As a leading chemical company, at Junyuan Petroleum Group we are committed to providing high-quality and innovative products to our customers around the world. However, delivering chemical samples to different countries and regions is not a simple task. It requires careful planning and execution, as well as compliance with various laws and regulations. To ensure the safety and legality of our sample shipments, we follow these steps: – We identify the type and hazard level of our chemical samples, and whether they need any special permits or certificates. – We choose the appropriate shipping service and mode of transportation, such as air, land or sea, that meet the international or domestic transport rules. – We use proper packaging materials and labels, to prevent leakage, damage or mishandling of our samples. – We fill out complete and accurate shipping documents, including the information of the recipient and the sender, as well as the name, quantity, hazard level and other relevant information of our samples. – We hand over the shipping documents and samples to the shipping service provider, pay the corresponding fees, and track the shipping status. By following these steps, we can ensure that our samples reach our customers in a timely and efficient manner, and that we maintain our reputation as a reliable and trustworthy partner. We are always ready to serve our customers with our best products and services. Some of our most popular products are n-Pentane, Isopentane, Cyclopentane, Blowing Agents, n-Hexane, Isohexane, n-Heptane, n-Butane and Isobutane. These products are widely used in the production of insulation materials, such as Polyurethane (PU) and Polystyrene (PS) foams. They have different properties and advantages, depending on the application and the desired insulation performance¹². For example, Cyclopentane offers an extremely high and lasting insulating effect, as it remains partially in the cells of PU and PIR foams after foaming¹. N-Pentane and Iso-Pentane have a lower insulating effect than Cyclopentane, but they are more stable and the individual cells are firmer and finer². Blowing Agents are mixtures of different Pentanes, which can optimize the costs and foam properties¹. We test these products in our state-of-the-art laboratories, to ensure their quality and safety. We also customize the products according to the specific needs and preferences of our customers. For example, we can adjust the purity, viscosity, boiling point, and flash point of the products, to suit different applications and climates. The typical amount of samples that our customers request is around 250 milliliters, but this may vary depending on the product and the customer’s requirements. We always try to accommodate the requests of our customers, as long as they are reasonable and legal. We also provide technical support and guidance, to help our customers use our products effectively and efficiently.

Source:
(1) Which Pentanes are suitable for the production of insulating materials?
(2) Which Pentane Blowing Agent is Best for Your Application?
(3) Cyclopentane, as a blowing agent in Polyurethane (PU) foams, is the …. https://junyuanpetroleumgroup.com/chemical-manufacturer-supplier-distributor/cyclopentane-as-a-blowing-agent-in-polyurethane-pu-foams-is-the-most-important-raw-material-for-high-performance-insulation-in-refrigerators/.
(4) N-Heptane Vs N-Pentane

n-Pentane, Isopentane and Cyclopentane are all saturated hydrocarbons that have five carbon atoms. They have different molecular structures and physical properties, which make them suitable for different uses. Some of the common applications for these Pentane isomers are:

• Blowing agents for insulation materials: Pentanes are the foaming agent of choice for producing Polyurethane (PU) and Polystyrene (PS) insulation boards. They have a high performance and sustainability, as they do not deplete the ozone layer or contribute to global warming. Cyclopentane has the best insulating effect, while n-Pentane and Isopentane have more stable and finer foam cells².
• Refrigerants: n-Pentane can be used as a refrigerant in air conditioning or refrigeration systems, as an alternative to ammonia or fluorinated hydrocarbons. It has a low boiling point and a high latent heat of vaporization, which means it can absorb a lot of heat when it changes from liquid to gas¹.
• Non-polar solvents: Pentanes are almost insoluble in water, but show very good solubility or unlimited miscibility with many organic solvents such as paraffins, ethers, esters, aromatics or chlorinated hydrocarbons. They are also very volatile, which means they evaporate quickly and leave no residue. Therefore, they are suitable for cleaning in the aerospace, automobile, electronic, and defense manufacturing industries¹⁵.
• Process media for polyethylene and polypropylene: Pentanes can be used as process media for the production of polyethylene (PE, LLDPE) and polypropylene (PP), which are widely used plastics. Pentanes help to control the molecular weight, branching and crystallinity of the polymers, which affect their mechanical and thermal properties¹.

These are some of the main applications for n-Pentane, Isopentane and Cyclopentane. I hope this overview is helpful for you.

Choosing between n-Pentane, Isopentane and Cyclopenane depends on the intended use. Here are some general differences between them:

• Pentane is a colorless, volatile liquid, mainly used for chemical experiments, solvent and solvent mixture preparation, and also an important raw material in the petroleum industry.
• When buying pentane, you should pay attention to the following aspects:
  • Purity: The higher the purity of pentane, the better its performance and quality, but the higher the price. According to different uses, you can choose different purity grades, such as AR, CP, GCS, GR, HPLC, agricultural residue grade, etc.
  • Packaging: Pentane is a flammable liquid and should be packed and stored in suitable sealed containers to prevent leakage and fire. Generally speaking, the packaging specifications of pentane are 200L steel drums and ISO tank containers.
  • Price: The price of pentane is affected by many factors such as market supply and demand, raw material cost, transportation cost, etc., generally ranging from hundreds of USD to thousands of USD. When buying, you should compare the quotations of different manufacturers and channels, and choose products with high cost performance.
  • Manufacturer: There are many manufacturers of pentane, and there are great differences in production scale, technology level, product quality, etc. You should fully understand the qualifications, reputation, after-sales service, etc. of the manufacturers when buying. You can choose regular, professional and reliable manufacturers through the Internet, industry associations, peer recommendations, etc.

SINOPETROCHEM reported on April 19th that the EXW quotation for pentane foaming agents (with a total pentane content >99%) in the Chinese market is CNY 7,350/MT, and production and sales are normal.

April 19, 2023 USD TO CNY TODAY

Actual USD to CNY exchange rate equal to 6.8750 Chinese Yuans per 1 Dollar.

Pentane is colourless with a very low odour and high volatility thanks to its low, narrow boiling range – it is among the lowest boiling hydrocarbon liquids and so evaporates at a very high rate. It is used principally as a blowing agent in foam production, as a propellant in aerosols and as reaction media for polymerisation processes.

Isopentane, Cyclopentane and Normal Pantene Blend Market Growth and Share Research 2023 | by Industry Types [Pentane 85/15, Pentane 80/20], and Applications [EPS Blowing Agent, Electronic Cleaning ,Chemical Solvent], Global Cyclopentane, Isopentane and Normalpentane Blend key players include Shell, Phillips 66, Junyuan Petroleum Group, ExxonMobil Chemical, TOP Solvent, etc.

China is the largest market, with a share over 30Percent, followed by Europe and North America, both have a share about 50Percent.
In terms of product, Pentane 60/40 is the largest segment, with a share over 30Percent. And in terms of application, the largest application is EPS Blowing Agent
, followed by Chemical Solvent, Electronic Cleaning, etc.

Cyclo-isopentane polyurethane foam insulation meets EU ROHS directive for a green and safe environment. Optimized hydrocarbon refrigeration system. As a blowing agent, cyclo- pentane has been confirmed as a long-term alternative to. R11. The mixture of isopentane and pentane was also.

Junyuan Petroleum Group is one of the largest n-Pentane, Isopentane and Cyclopentane manufacturers in China and your partner for tailor-made n-Pentane, iso-Pentane, Cyclopentane and blends.

Product Name: Cyclopentane, 95%

CAS: 287-92-3

IUPAC Name: cyclopentane

Molecular Formula:C5H10

InChI Key: RGSFGYAAUTVSQA-UHFFFAOYSA-N

SMILES:C1CCCC1

Molecular Weight (g/mol):70.14

Synonym: cyclopentane pentamethylene zyklopentan ciclopentano hsdb 62

Refractive Index: 1.4030-1.4090 @ 20C

Appearance (Color): Clear colorless

Form: Liquid

Assay (GC): ≥95.0%

Identification (FTIR): Conforms

Description

Cyclopentane is the lightest non-polar cycloalkane solvent used by the chemical industry. Its cyclical structure provides a higher solubility coefficient than branched or linear hydrocarbons, while its low molecular weight results in one of the lowest heat of vaporization values a among non-aromatic hydrocarbon solvents.

Features

• High solubility coefficient

• non polar

• low heat vaporization

Cyclopentane is used as green blowing agent and involved in the production of polyurethane insulating foam, which is used in refrigerators, freezers, water heaters, construction panels, insulated pipes and roofs. As a lubricant, it finds applications in computer hard drives and outer space equipment due to its low volatile nature. It is widely useful in the preparation of resin, adhesives and pharmaceutical intermediate. It is an additive in gasoline. Since it is a halogen free compound and has zero-ozone depletion potential, it replaces the conventionally used chloro fluoro carbon (CFC) in refrigeration and thermal insulation.

Applications

Cyclopentane is used as green blowing agent and involved in the production of polyurethane insulating foam, which is used in refrigerators, freezers, water heaters, construction panels, insulated pipes and roofs. As a lubricant, it finds applications in computer hard drives and outer space equipment due to its low volatile nature. It is widely useful in the preparation of resin, adhesives and pharmaceutical intermediate. It is an additive in gasoline. Since it is a halogen free compound and has zero-ozone depletion potential, it replaces the conventionally used chloro fluoro carbon (CFC) in refrigeration and thermal insulation.

Solubility

Miscible with ethanol, ether and acetone. Slightly miscible with water.

Notes

Avoid heat, direct sunlight, flames and sparks. Incompatible with strong oxidizing agents.

RUO – Research Use Only

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The Oigin of Cyclopentane
A colorless, water-insoluble liquid, C5H10, obtained from petroleum and used chiefly as a solvent. Cyclopentane is a flammable liquid and its vapors can be explosive. Cyclopentane has a bond angle of about 108°C. This minimal ring strain for cyclopentane makes it a more stable compound.

Cyclopentane is in the class of cycloalkanes, being alkanes that have one or more carbon rings. It is formed by cracking cyclohexane in the presence of alumina at a high temperature and pressure.

Cyclopentane is a twisted ring in the form of an “envelope” so that one of the carbon atoms is out of the plane of the ring.

Cyclopentane is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S.

Cyclopentane is formed from pentane and is an alicyclic hydrocarbon compound that falls in the category of an alkane.

Cyclopentane is treated with chlorine in the presence of light or heat to form chloro cyclopentane which then reacts with KOC(CH3)3 forming cyclopentene. Cyclopentane has a bond angle of about 108o. This minimal ring strain for cyclopentane makes it a more stable compound. Besides, this compound occurs as a colourless liquid, and it is flammable. Moreover, it has a petrol-like odour. Cyclopentane is a simple hydrocarbon. If 0.0956 g of the compound is combusted in oxygen, 0.300 g of carbon dioxide and 0.123 g of water are produced.

Boiling point: 49 °C
Melting point: −94 °C
Molecular formula: C5H10
Other names: pentamethylene

Cyclopentane makes important contribution to energy efficiency. Junyuan Petroleum Group is a leading manufacturer of Pentanes in China.