Tag Cyclopentane

Price of Pentane Blends in China Market Today•2023/04/19

SINOPETROCHEM reported on April 19th that the EXW quotation for pentane foaming agents (with a total pentane content >99%) in the Chinese market is CNY 7,350/MT, and production and sales are normal.

April 19, 2023 USD TO CNY TODAY

Actual USD to CNY exchange rate equal to 6.8750 Chinese Yuans per 1 Dollar.

SINOPETROCHEM reported on April 19th that the EXW quotation for pentane foaming agents (with a total pentane content of>99%) in the Chinese market is 7,350 yuan/ton, and production and sales are normal.
Price Trend of Pentanes

Pentane is colourless with a very low odour and high volatility thanks to its low, narrow boiling range – it is among the lowest boiling hydrocarbon liquids and so evaporates at a very high rate. It is used principally as a blowing agent in foam production, as a propellant in aerosols and as reaction media for polymerisation processes.

Isopentane, Cyclopentane and Normal Pantene Blend Market Growth and Share Research 2023 | by Industry Types [Pentane 85/15, Pentane 80/20], and Applications [EPS Blowing Agent, Electronic Cleaning ,Chemical Solvent], Global Cyclopentane, Isopentane and Normalpentane Blend key players include Shell, Phillips 66, Junyuan Petroleum Group, ExxonMobil Chemical, TOP Solvent, etc.

China is the largest market, with a share over 30Percent, followed by Europe and North America, both have a share about 50Percent.
In terms of product, Pentane 60/40 is the largest segment, with a share over 30Percent. And in terms of application, the largest application is EPS Blowing Agent
, followed by Chemical Solvent, Electronic Cleaning, etc.

Cyclo-isopentane polyurethane foam insulation meets EU ROHS directive for a green and safe environment. Optimized hydrocarbon refrigeration system. As a blowing agent, cyclo- pentane has been confirmed as a long-term alternative to. R11. The mixture of isopentane and pentane was also.

Junyuan Petroleum Group is one of the largest n-Pentane, Isopentane and Cyclopentane manufacturers in China and your partner for tailor-made n-Pentane, iso-Pentane, Cyclopentane and blends.

Cyclopentane Shipment Ongoing 12:00•2023/04/16

Product Name: Cyclopentane, 95%

CAS: 287-92-3

IUPAC Name: cyclopentane

Molecular Formula:C5H10

InChI Key: RGSFGYAAUTVSQA-UHFFFAOYSA-N

SMILES:C1CCCC1

Molecular Weight (g/mol):70.14

Synonym: cyclopentane pentamethylene zyklopentan ciclopentano hsdb 62

Refractive Index: 1.4030-1.4090 @ 20C

Appearance (Color): Clear colorless

Form: Liquid

Assay (GC): ≥95.0%

Identification (FTIR): Conforms

Description

Cyclopentane is the lightest non-polar cycloalkane solvent used by the chemical industry. Its cyclical structure provides a higher solubility coefficient than branched or linear hydrocarbons, while its low molecular weight results in one of the lowest heat of vaporization values a among non-aromatic hydrocarbon solvents.

Features

• High solubility coefficient

• non polar

• low heat vaporization

Cyclopentane is used as green blowing agent and involved in the production of polyurethane insulating foam, which is used in refrigerators, freezers, water heaters, construction panels, insulated pipes and roofs. As a lubricant, it finds applications in computer hard drives and outer space equipment due to its low volatile nature. It is widely useful in the preparation of resin, adhesives and pharmaceutical intermediate. It is an additive in gasoline. Since it is a halogen free compound and has zero-ozone depletion potential, it replaces the conventionally used chloro fluoro carbon (CFC) in refrigeration and thermal insulation.

Applications

Cyclopentane is used as green blowing agent and involved in the production of polyurethane insulating foam, which is used in refrigerators, freezers, water heaters, construction panels, insulated pipes and roofs. As a lubricant, it finds applications in computer hard drives and outer space equipment due to its low volatile nature. It is widely useful in the preparation of resin, adhesives and pharmaceutical intermediate. It is an additive in gasoline. Since it is a halogen free compound and has zero-ozone depletion potential, it replaces the conventionally used chloro fluoro carbon (CFC) in refrigeration and thermal insulation.

Solubility

Miscible with ethanol, ether and acetone. Slightly miscible with water.

Notes

Avoid heat, direct sunlight, flames and sparks. Incompatible with strong oxidizing agents.

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What is Cyclopentane?

The Oigin of Cyclopentane
A colorless, water-insoluble liquid, C5H10, obtained from petroleum and used chiefly as a solvent. Cyclopentane is a flammable liquid and its vapors can be explosive. Cyclopentane has a bond angle of about 108°C. This minimal ring strain for cyclopentane makes it a more stable compound.

Cyclopentane is in the class of cycloalkanes, being alkanes that have one or more carbon rings. It is formed by cracking cyclohexane in the presence of alumina at a high temperature and pressure.

Cyclopentane is a twisted ring in the form of an “envelope” so that one of the carbon atoms is out of the plane of the ring.

Cyclopentane is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S.

Cyclopentane is formed from pentane and is an alicyclic hydrocarbon compound that falls in the category of an alkane.

Cyclopentane is treated with chlorine in the presence of light or heat to form chloro cyclopentane which then reacts with KOC(CH3)3 forming cyclopentene. Cyclopentane has a bond angle of about 108o. This minimal ring strain for cyclopentane makes it a more stable compound. Besides, this compound occurs as a colourless liquid, and it is flammable. Moreover, it has a petrol-like odour. Cyclopentane is a simple hydrocarbon. If 0.0956 g of the compound is combusted in oxygen, 0.300 g of carbon dioxide and 0.123 g of water are produced.

Boiling point: 49 °C
Melting point: −94 °C
Molecular formula: C5H10
Other names: pentamethylene

Cyclopentane makes important contribution to energy efficiency. Junyuan Petroleum Group is a leading manufacturer of Pentanes in China.

Top 5 Uses of Pentane

Top 5 Uses of Pentane

Pentane is a cost-effective liquid that has several different industrial and laboratory applications.

  1. Laboratory Solvents

They are the most volatile liquid alkanes (at room temperature). Because of this, they are commonly used in laboratories as solvents. Although, due to their lack of functionality and non-polarity, they only dissolve other nonpolar and alkyl-rich compounds. Pentanes are miscible with other solvents like ethers, aromatics, and chlorocarbons.

  1. Chromatography

Pentane is commonly used in chromatography – which is a laboratory technique to separate components in a mixture. The mixture is passed in a suspension or solution through a medium where the components each move at different rates.

  1. Blowing Agent

Pentane is used as the primary blowing agent in the production of foams like polystyrene. A blowing agent is a substance that is capable of producing a cellular structure through a foaming process. These foams are often used as insulating material in refrigerators and heating pipes

  1. Binary Fluid

Because of its low boiling point, pentane is used in geothermal power stations as a binary fluid.

  1. Industrial Ingredient Uses

Due to its ready availability and low cost, pentane is also used as a solvent in many common products like pesticides. It can also be used in making other chemicals, plastics, and low-grade thermometers. Acid-catalyzed isomerization can produce isopentane, which can be used in making fuels.

The price of EPS products in the Chinese market today 2023/03/10

The price of EPS products in the Chinese market today is CNY10,122.8/MT, down -0.29% from the previous trading day

Pentane is the most common expansion agent in EPS production. Low concentration of pentane can be trapped during production, inside the closed cells of EPS. By the end of the production cycle, EPS products may still contain 1-2% of Pentane by weight.

What is EPS foam made of?
WHAT IS EPS? Expanded Polystyrene (EPS) is a rigid, closed cell, thermoplastic foam material produced from solid beads of polystyrene, which is polymerised from styrene monomer and contains an expansion gas (pentane) dissolved within the polystyrene bead.

type of foam is EPS?
expanded polystyrene foam
The foam that you formerly knew as styrofoam is actually expanded polystyrene foam or EPS. This material is made from polystyrene, a plastic that’s often used to make clear products like food packaging or lab equipment.

What are the different types of polystyrene?

What Are The Different Types of Polystyrene? Three major types of polystyrene include polystyrene foam, regular polystyrene plastic, and polystyrene film. Amongst the different types of foam are expanded polystyrene (EPS) and extruded polystyrene (XPS).

Properties of Pentane Blowing Agent and Properties of Rigid Polyurethane Foam

Polyurethane foam is widely used in construction, refrigeration, piping and other fields due to its low density, good thermal insulation, low water absorption, low toxicity, and good processability. The blowing agent is an important auxiliary agent for the production of polyurethane foam plastics. Since the second-generation blowing agent HCFC-141b has an ODP value of 0.11 and a GWP value of 725, it has a great impact on the ozone layer and the greenhouse effect, so it can only be used as a transitional agent. use of sex substitutes. According to China’s polyurethane foam industry HCFC-141b phase-out plan (second phase), the polyurethane foam industry will gradually reduce HCFC-141b consumption based on the results achieved in the first phase, and will achieve industry-wide phase-out by the end of 2025. At present, the commonly used substitutes for HCFC-141b blowing agent mainly include pentane, water, hydrofluorocarbon (HFC), liquid carbon dioxide, hydrofluoroolefin (HFO) and methyl formate. Among them, pentane is widely used due to its advantages of environmental protection, low price, and easy availability. However, pentane is flammable and explosive, and is a dangerous chemical. The use of this kind of blowing agent requires safety renovation of production equipment and workshops. Although the initial investment of pentane foaming replacement technology is relatively high, in the long run, the comprehensive economic benefits are obvious, and it is an ideal substitute for HCFC-141b.

Types of Pentanes and Pentane Blowing Agents

Types of Pentane and Pentane Blowing Agents

Pentanes include n-pentane, isopentane and cyclopentane. The molecular formula is C5H12 and the molecular weight is 72.15. Cyclopentane, also known as “pentamethylene”, is a cycloalkane with the molecular formula C5H10. Molecular weight 70.13. flammable liquid.

The high-purity n-pentane produced by Junyuan Petroleum Group has a purity of up to 99.5%, a n-butane content of less than 0.01%, an isopentane content of less than 0.2%, and a C6 content of less than 0.3%.

N-pentane and isopentane are separated from oilfield light hydrocarbons through high-efficiency rectification. N-pentane can be used as a desorbing agent in the dewaxing process of molecular sieves, and it can be used as a high-efficiency blowing agent for expandable polystyrene after blending with isopentane in different proportions to meet the requirements of different foaming degrees. It can be mixed with cyclopentane, etc. as a polyurethane foaming agent. Isopentane can be used as blowing agent for expandable polystyrene, foaming agent for polyurethane foam system, deasphalting solvent, solvent for catalyst in polyethylene production, etc. Generally blended with cyclopentane. Used as rigid polyurethane foam blowing agent. Cyclopentane (molecular formula C5H10) is a saturated hydrocarbon with a melting point of -94.4°C and a boiling point of 49.3°C. It is stable and insoluble in water, but soluble in most organic solvents such as ethanol, ether, benzene, carbon tetrachloride, and acetone. It is used as a solvent, as a foaming agent (instead of Freon) in the preparation of polyurethane foam, and as a standard substance for chromatographic analysis.

CAS: 287-92-3
Molecular formula: C5H10
Molecular weight: 70.13
Boiling point: 50℃
Melting point: -94-49℃
Chinese name: cyclopentane, pentamethylene, cyclopentamethylene
English name: ,Cyclopentane, pentamethylene, Cyclopentane,HPLC Grade, Cyclopentan, Cyclopcntan
Nature description:
Colorless liquid, melting point -93.9°C, boiling point 49.26°C, relative density 0.7460 (20/4°C), refractive index 1.4068, flash point -37°C. It can be miscible with organic solvents such as alcohol and ether, but insoluble in water.
production method:
Cyclopentane is a component of petroleum ether with a boiling point range of 30-60°C, the content is generally 5%-10%, and it is distilled at atmospheric pressure with a reflux ratio of 60:1 in a tower with a height of 8m. Isopentane and n-pentane can be further fractionated to obtain cyclopentane with a purity of more than 98%. Cyclopentane can also be prepared by reduction of cyclopentanone or catalytic hydrogenation of cyclopentadiene.
Uses:
It is used as a solvent for solution polymerization of polyisoprene rubber and a solvent for cellulose ether, as a substitute for freon for insulation materials in refrigerators and freezers and as a foaming agent for other hard PU foams, and as a reference material for chromatographic analysis.
The pentane foaming agent series products produced by Junyuan Petroleum Group are mainly composed of n-pentane, isopentane and cyclopentane. The total content of pentane is over 98%. It can be blended with cyclopentane into about 30 different types of products, which are mainly used as plastic foaming agents, and can also be used as industrial solvents, extractants and chemical raw materials.

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n-Pentane Market Size, Share, Industry Forecast 2026

Pentane is an organic compound with 5 carbon atoms. There are three structural isomers
of pentane of which n-pentane is a long chained isomer. Pentane is inexpensive, non-polar,
and miscible in almost all non-polar solvents. Pentane is generally employed in fuels,
industrial applications like solvents, manufacturing of polystyrene foam, working medium
and other. Moreover, n-pentane has laboratory applications and is used as solvent. It is
also used in liquid chromatography.
Increasing demand from industrial sector for n-pentane due to the high volatility,
miscibility with non-polar compounds like chlorocarbons, olefins, ethers shall drive the
market. Additionally, the lower cost of n-pentane compared to other industrial solvents
shall boost the market demand. Pentane is also an important component of fuels.
Increasing demand for fuels from all over the world shall foster the market growth.
However, n-pentane is a non-polar solvent which is dissolved only in non-polar and alkyl
rich compounds. They lack in functionality and this is expected to hinder the market
growth.

MARKET SEGMENTATION:
Based on product type, the global n-pentane market is segmented into pentane 85/15,
pentane 60/40, pentane 50/50, pentane 20/80, pentane 80/20, pentane 70/30. Based on
application, is segmented into bowing agent, electronic cleaning, chemical solvent, aerosol
propellant, solvent, and others.
From a geographical standpoint, the market is categorized into North America, Europe,
Asia Pacific, Latin America, and the Middle East and Africa.
KEY PLAYERS COVERED:
The global n-Pentane market consists of global & regional players operating. Some of the
key players in the market include, Chevron Phillips Chemical Company LP, Exxonmobil,
Shell, Top Solvent Co., Ltd, South Hampton Resources, Diversified Cpc International, LG
Chem, Aeropres Corporation, Jun Yuan Petroleum Group, and others.
KEY INSIGHTS
New Advancements in Production Technologies
Key Trends in the N-Pentane Market
New Product Launches, Expansions, Key Players
Ranking of Key Players in the Market
REGIONAL ANALYSIS:
The market has been segmented into North America, Europe, Asia Pacific, Latin America,
and Middle East & Africa. North America is expected to hold the largest share in market.
Rise in demand from industrial sector for solvent shall boost the regional market. Asia
Pacific is estimated to hold significant share attributed to large chemical manufacturing
base. High demand from industrial sector for manufacturing polystyrene foam, PU foam
and other products shall foster the market. Europe is expected to show considerable
growth due to the increasing demand for fuel. Increasing production of vehicles is further
rising the demand for fuel. This shall foster the market growth in Europe. Latin America
and Middle East & Africa shall exhibit sluggish growth by the end of forecast period.

SEGMENTATION
ATTRIBUTE DETAILS
By Product Type
Pentane 85/15
Pentane 60/40
Pentane 50/50
Pentane 20/80
Pentane 80/20
Pentane 70/30
By Application
Bowing Agent
Electronic Cleaning
Chemical Solvent
Aerosol Propellant
Solvent
Others


By Geography
North America (U.S., and Canada)
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N-PENTANE INDUSTRY DEVELOPMENTS
Junyuan Petroleum Group manufactures a wide range of solvents and fluids for industrial use. n-Pentane is one of the solvent available in different composition and is widely used in industrial sector.

Methods to Produce Isoprene by Dehydrogenation

There are two methods to produce isoprene by dehydrogenation: isopentane dehydrogenation and isopentene catalytic dehydrogenation. 1、 Isopentane dehydrogenation method The two-step catalytic dehydrogenation method of isopentane was first developed by the former Soviet Union and was industrialized in 1968. The raw material isopentene used in the isopentene dehydrogenation process is from catalytic cracking or straight-run gasoline. The process is mainly divided into three steps: first, the isopentane is dehydrogenated to isopentene, and a fluidized bed reactor similar to catalytic cracking is used, and the catalyst is spherical chromium-alumina oxide; Then isoprene is obtained by catalytic dehydrogenation of isoprene, and the plate-shaped calcium-nickel-phosphoric acid catalyst and adiabatic fixed-bed reactor are used; Finally, the dehydrogenation product is extracted and distilled with dimethylformamide or acetonitrile in two extractive distillation columns to obtain crude isoprene, and then the high-purity product is obtained after alkali treatment, hydrogenation and acetylene removal. In order to obtain the conversion rate beneficial to industrial production, the reaction must be carried out at high temperature (above 500~600 ℃), resulting in the increase of side reactions such as pyrolysis and isomerization. Therefore, although the raw materials of this method are cheap and easy to obtain, the cost and consumption quota are high, the process for preparing high-purity products is complex, and the development prospect is lacking. At present, only some enterprises in Russia and Eastern Europe apply this method to produce isoprene, with a total production capacity of about 300000 t/a. 2、 There are three isomers of isopentene by catalytic dehydrogenation of isopentene: 2-methyl-1-butene, 2-methyl-2-butene and 3-methyl-1-butene, of which 2-methyl-2-butene is the most suitable precursor for the synthesis of isoprene. In 1961, Shell Company of the United States built a 18000 t/a isoprene production unit using isoprene catalytic dehydrogenation method, and the production capacity of this method has reached 190000 t/a. The process flow is divided into three steps: extracting and separating isopentene from C5 fraction, a by-product of the catalytic cracking unit of the refinery; Isopentene was dehydrogenated at 600 ℃ in a fixed-bed adiabatic reactor using iron oxide, chromium oxide and carbonate catalysts; The dehydrogenation product is extracted, distilled and refined to obtain isoprene product with purity of 99.2%~99.7%. This method can use isopentene (10%~30%) with a wide range of mass fraction as raw material. Among the many methods for producing isoprene, extractive distillation has certain advantages in technology and economy. In economy, only alkenal method can be compared with extractive distillation, and the production cost of other methods is higher. Summary: From an economic point of view, the isoprene dehydrogenation technology developed by the former Soviet Union to produce isoprene has been declining and cannot be compared with the cracking C5 separation method. For the students participating in the chemical design competition, it is even more difficult to check the documents of the former Soviet Union decades ago. Even if they find them, they are still in Russian, and they can’t understand them. From a technical point of view, the reaction part is similar to the catalytic cracking unit, which is extremely complex, with many side reactions, more complex components and great difficulty in product separation. It is conceivable that such a huge workload and technical difficulty will defeat a large number of heroes.

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