Global Supply of n-Hexane for Industrial and Polymer Applications

Meta Description:
Reliable high-purity n-Hexane (CAS 110-54-3) for LLDPE and HDPE polymerization, offering consistent quality, low impurities, and global supply support for industrial and chemical applications.

Overview

n-Hexane is a straight-chain hydrocarbon solvent widely used in industrial and polymer processes. Its low polarity, high volatility, and excellent solvency make it ideal for applications requiring high purity and consistent performance.

Key Properties:

• CAS Number: 110-54-3
• Chemical Formula: C6H14
• Boiling Point: ~68.7°C
• Density: ~0.659 g/cm³ at 20°C
• Flash Point: -22°C
• Purity Grades Available: 60%, 70%, 80%, 90%, 95%, 99%

High-purity n-Hexane is especially important in polyethylene polymerization, where the presence of aromatics or branched hydrocarbons can negatively affect catalyst activity and polymer quality.

Industrial Applications

1. Polyethylene Polymerization (LLDPE & HDPE)

n-Hexane serves as a process solvent in solution and slurry polymerization:

• Acts as a carrier for catalysts and co-catalysts.
• Provides efficient heat transfer during exothermic reactions.
• Dissolves additives without interfering with polymerization.
• Boiling point (~69°C) allows easy recovery and recycling.

Purity Considerations:

• Recommended grades for polymerization: 95–99% purity.
• Low aromatics, sulfur, and water content are critical to avoid catalyst poisoning and ensure consistent polymer properties.

2. Other Industrial Uses

• Cleaning and degreasing of polymer equipment.
• Intermediate solvent in chemical synthesis.
• Extraction and other low-boiling, non-polar solvent applications.

Product Grades and Suitability

Grade	Purity	Iso-/Branched Hexane	Aromatics	Sulfur (ppm)	Water (ppm)	Boiling Range (°C)	Suitability for LLDPE/HDPE
n-Hexane 60%	60%	Moderate	≤1%	≤5	≤200	65–70	Not suitable – too low purity
n-Hexane 70%	70%	Moderate	≤1%	≤5	≤150	65–70	Marginal – may affect polymerization
n-Hexane 80%	80%	Low	≤0.5%	≤2	≤100	66–70	Limited use; may require pre-treatment
n-Hexane 90%	90%	Low	≤0.1%	≤1	≤50	67–70	Suitable for some industrial applications
n-Hexane 95%	95%	Very low	<0.1%	<1	<50	68–70	Suitable for LLDPE/HDPE polymerization
n-Hexane 99%	99%	Minimal	<0.05%	<0.5	<20	68–70	Ideal – polymer-grade high purity

Note: Hydrotreated heavy naphtha (CAS 64742-49-0) is not suitable for precision polymerization due to impurities and aromatics.

Why Choose Our n-Hexane?

• Catalyst-Friendly: Ultra-low sulfur and aromatic content prevents catalyst poisoning.
• Consistent Quality: Stable boiling range ensures predictable polymer properties.
• Versatile Applications: Suitable for industrial, laboratory, and polymer-grade uses.
• Global Supply: Flexible packaging and shipping options support uninterrupted production.

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Abstract

This article presents a clear and concise overview of two important product lines: the n-Pentane series (90, 95, and 99 percent purity) and pentane-based blowing agents (F3 through F8). It explores their key applications in foam manufacturing, chemical processes, and other industries, while also highlighting their performance characteristics such as low sulfur content and high Saybolt color index. In addition, this piece emphasizes the products’ environmental benefits and suitability for sustainable development.

Keywords:

n-Pentane, Pentane Blowing Agent, Foam Manufacturing, Chemical Solvent, Sustainable Development, Low Sulfur, High Purity

Introduction

n-Pentane and its related blowing agent formulations are widely used in a range of industrial processes. They play a particularly significant role in foam production, especially for polyurethane (PU), polystyrene (PS), and polyether-based foams. Due to their favorable physical and chemical properties, these pentane products have also found their way into diverse applications such as chemical synthesis, pharmaceutical solvents, refrigerant blends, and laboratory standards.

n-Pentane Series: Grades and Characteristics

The n-Pentane series typically includes three grades: 90% n-Pentane, 95% n-Pentane, and 99% n-Pentane. All three are colorless, low-odor liquids with Saybolt color values of at least 28, indicating a very high degree of purity in terms of visual appearance. Their densities, measured at 20°C, generally range from about 620 to 630 kg/m³.

• Purity Levels:

• 90% n-Pentane contains at least 90% of the n-Pentane isomer.

• 95% n-Pentane raises that content to 95%.

• 99% n-Pentane provides an even higher level of purity, making it suitable for specialized applications such as chemical reagents, calibration standards, and high-end solvent needs.

• Quality Indicators:

• Bromine Index: For all three grades, the bromine index is typically under 100 mgBr/100 g, reflecting minimal levels of unsaturated compounds.

• Water Content: Ranges from below 150 ppm in the 90% and 95% grades to under 100 ppm in the 99% grade, ensuring a low moisture environment for sensitive processes.

• Sulfur Content: Less than 5 ppm across all grades, which is crucial for processes requiring low sulfur to minimize catalyst poisoning and unwanted by-products.

Pentane Blowing Agents: F3 to F8

Besides the pure n-Pentane series, specialized pentane blowing agents are formulated for foam production. These products blend n-Pentane and iso-Pentane in specific ratios, allowing manufacturers to fine-tune their foam properties. Common variants include F3, F4, F5, F6, F7, and F8, each offering distinct proportions of n-Pentane and iso-Pentane.

• n-Pentane Content:

Ranges from about 30±2% in F3 up to 80±2% in F8.

• iso-Pentane Content:

Adjusted accordingly, typically running higher when the n-Pentane portion is lower, and vice versa.

• Density:

Generally falls between 615 and 630 kg/m³ at 20°C, ensuring consistency in handling and blending.

• Bromine Index, Water Content, Sulfur Content:

All remain within strict limits (bromine index ≤100 mgBr/100 g, water ≤150 ppm, sulfur ≤5 ppm), aligning with stringent quality and environmental requirements.

Main Applications

1. Foam Manufacturing:

• Polyurethane (PU) Foams: Pentane is a preferred blowing agent for producing rigid and flexible PU foams, used in insulation, automotive components, and furniture.

• Polystyrene (PS) Foams: Particularly in the construction sector, pentane blends help achieve the desired density and thermal insulation performance.

• Polyether Foams: The balance of n-Pentane and iso-Pentane ensures precise control over foam cell structure and stability.

2. High-Purity 99% n-Pentane Applications:

• Chemical Reagent: Ideal for laboratory research, quality control, and analytical procedures.

• Standard Reference Material: Useful as a calibration solvent or reference compound in chromatography.

• Pharmaceutical Solvent: Provides a clean, low-sulfur solvent environment for sensitive chemical reactions.

• New Refrigerants and Polymerization Processes: Offers an environmentally friendly option in advanced chemical and polymer production.

Environmental and Safety Considerations

Modern industry places a strong emphasis on sustainability. The pentane family is known for having low sulfur content and minimal impact on the environment compared to older, less eco-friendly alternatives. However, due to their volatility and flammability, proper handling and storage are essential. Following established safety guidelines and using approved equipment can mitigate potential risks, ensuring a safer workplace and reducing environmental hazards.

Conclusion

n-Pentane products and pentane blowing agents offer versatile, high-performance solutions for a variety of industrial applications. Their consistently high quality—evident in factors such as minimal sulfur content, low moisture levels, and stable density—makes them a top choice for foam production, chemical synthesis, pharmaceutical applications, and beyond. Furthermore, their environmentally friendly profile aligns well with modern sustainability goals, paving the way for continued innovation and market growth.

By carefully selecting the appropriate grade or blowing agent blend, manufacturers can optimize production processes, enhance product performance, and contribute to more sustainable industrial practices. This focus on quality and eco-conscious design underscores the ongoing importance of n-Pentane and pentane-based blowing agents in both current and future applications.