Archives May 2025

A row of large industrial storage tanks at a manufacturing facility, designated for n-Hexane, n-Heptane, and Isohexane.

Comparison of n-Hexane, n-Heptane, and Isohexane: CAS Numbers, HS Codes, UN Numbers, and Applications

Keywords: n-Hexane, n-Heptane, Isohexane, CAS Number, HS Code, UN Number, Applications, Chemical Properties, Industrial Use

Abstract

This article provides a comparative analysis of n-Hexane, n-Heptane, and Isohexane in terms of their CAS numbers, HS codes, UN numbers, and practical applications. These hydrocarbons play crucial roles in industrial solvents, fuel additives, and chemical synthesis. Understanding their regulatory classifications and primary uses enables better decision-making in logistics, trade, and compliance.

Introduction

n-Hexane, n-Heptane, and Isohexane are key hydrocarbons used in various industrial applications, particularly in solvent extraction, chemical synthesis, and fuel formulation. While they share similar structures, their distinct properties define their applications and regulatory classifications.

Chemical Identifiers and Classification

ChemicalCAS NumberHS CodeUN Number
n-Hexane110-54-32901.10UN 1208
n-Heptane142-82-52902.20UN 1206
Isohexane107-83-52901.10UN 1262

Each compound has a unique CAS number, which serves as an international identifier in chemical databases. Their HS codes categorize them for international trade purposes, ensuring standardized tariffs and trade policies. The UN numbers indicate transportation hazards and are used for classifying hazardous materials under shipping regulations.

Applications

1. n-Hexane

  • Widely used as a solvent in industrial processes such as oil extraction, adhesives, and coatings.
  • Commonly found in degreasing agents due to its strong solvency properties.
  • Frequently used in laboratory settings for chromatography and chemical synthesis.

2. n-Heptane

  • Applied in octane rating determination for fuels, particularly in gasoline standardization.
  • Used as a non-polar solvent in chemical and pharmaceutical industries.
  • Functions as a cleaning agent for electronics and specialized machinery.

3. Isohexane

  • Primarily utilized in gasoline blending as a high-performance fuel component.
  • Used in polymer manufacturing and synthetic rubber production.
  • Commonly found in formulations requiring controlled volatility characteristics.

Conclusion

n-Hexane, n-Heptane, and Isohexane serve distinct roles in industrial applications, yet share common classifications for trade and regulatory purposes. Understanding their CAS numbers, HS codes, and UN numbers aids in navigating logistics and compliance requirements efficiently. The diverse applications of these hydrocarbons reinforce their significance in industries such as fuel refining, chemical processing, and manufacturing.

Comparison of UN Numbers, CAS Numbers, and HS Codes for n-Pentane, Isopentane, and Cyclopentane

This article provides a comprehensive comparison of three chemical compounds—n-Pentane, Isopentane, and Cyclopentane—based on their UN numbers, CAS numbers, and Harmonized System (HS) codes. These identifiers are crucial for safety regulations, chemical tracking, and international trade compliance. Understanding their distinctions helps industries manage transportation, storage, and customs procedures effectively.

Comparison Table

Chemical Compound | UN Number | CAS Number | HS Code

n-Pentane | UN 1265 | CAS 109-66-0 | 2901.10.10
Isopentane | UN 1265 | CAS 78-78-4 | 2901.10.90
Cyclopentane | UN 1146 | CAS 287-92-3 | 2902.19.00

Keywords

n-Pentane, Isopentane, Cyclopentane, UN Number, CAS Number, HS Code, Chemical Identification, International Trade, Chemical Safety, Transportation Regulations

This structured comparison allows professionals in chemistry, logistics, and trade to better navigate classification and compliance requirements.

Comparison of UN Numbers, CAS Numbers, and HS Codes for n-Pentane, Isopentane, and Cyclopentane

This article provides a comprehensive comparison of three chemical compounds—n-Pentane, Isopentane, and Cyclopentane—based on their UN numbers, CAS numbers, and Harmonized System (HS) codes. These identifiers are crucial for safety regulations, chemical tracking, and international trade compliance. Understanding their distinctions helps industries manage transportation, storage, and customs procedures effectively.

Comparison Table

Chemical Compound | UN Number | CAS Number | HS Code

n-Pentane | UN 1265 | CAS 109-66-0 | 2901.10.10
Isopentane | UN 1265 | CAS 78-78-4 | 2901.10.90
Cyclopentane | UN 1146 | CAS 287-92-3 | 2902.19.00

Keywords

n-Pentane, Isopentane, Cyclopentane, UN Number, CAS Number, HS Code, Chemical Identification, International Trade, Chemical Safety, Transportation Regulations

This structured comparison allows professionals in chemistry, logistics, and trade to better navigate classification and compliance requirements.

Comparison of UN Numbers, CAS Numbers, and HS Codes for n-Pentane, Isopentane, and Cyclopentane

This article provides a comprehensive comparison of three chemical compounds—n-Pentane, Isopentane, and Cyclopentane—based on their UN numbers, CAS numbers, and Harmonized System (HS) codes. These identifiers are crucial for safety regulations, chemical tracking, and international trade compliance. Understanding their distinctions helps industries manage transportation, storage, and customs procedures effectively.

Comparison Table

Chemical Compound | UN Number | CAS Number | HS Code

n-Pentane | UN 1265 | CAS 109-66-0 | 2901.10.10
Isopentane | UN 1265 | CAS 78-78-4 | 2901.10.90
Cyclopentane | UN 1146 | CAS 287-92-3 | 2902.19.00

Keywords

n-Pentane, Isopentane, Cyclopentane, UN Number, CAS Number, HS Code, Chemical Identification, International Trade, Chemical Safety, Transportation Regulations

This structured comparison allows professionals in chemistry, logistics, and trade to better navigate classification and compliance requirements.

Comparison of UN Numbers, CAS Numbers, and HS Codes for n-Pentane, Isopentane, and Cyclopentane

This article provides a comprehensive comparison of three chemical compounds—n-Pentane, Isopentane, and Cyclopentane—based on their UN numbers, CAS numbers, and Harmonized System (HS) codes. These identifiers are crucial for safety regulations, chemical tracking, and international trade compliance. Understanding their distinctions helps industries manage transportation, storage, and customs procedures effectively.

Comparison Table

Chemical Compound | UN Number | CAS Number | HS Code

n-Pentane | UN 1265 | CAS 109-66-0 | 2901.10.10
Isopentane | UN 1265 | CAS 78-78-4 | 2901.10.90
Cyclopentane | UN 1146 | CAS 287-92-3 | 2902.19.00

Keywords

n-Pentane, Isopentane, Cyclopentane, UN Number, CAS Number, HS Code, Chemical Identification, International Trade, Chemical Safety, Transportation Regulations

This structured comparison allows professionals in chemistry, logistics, and trade to better navigate classification and compliance requirements.

Aerial view of pentane, hexane and heptane plant

The Commercial Legend of n-Hexane: From Laboratory Discovery to Global Supply Chain

Chapter One: A Serendipitous Discovery in the Laboratory

In the late 19th century, German chemists, during an oil distillation experiment, unexpectedly isolated a colorless and highly volatile liquid hydrocarbon mixture. Spectral analysis confirmed that it was a straight-chain alkane composed of six carbon atoms—n-Hexane. Initially regarded as a “supporting character” in laboratories, scientists soon realized that this compound’s potential was far from fully tapped.

Chapter Two: The Industrial Revolution’s “Invisible Driver”

In the early 20th century, the rise of the rubber industry marked n-Hexane’s first moment in the spotlight. Natural rubber processing required powerful solvents to soften the latex, and n-Hexane quickly stood out due to its high solvency, relatively low toxicity (compared to other solvents), and easy volatility. American rubber companies were the first to mass-produce it, and demand for n-Hexane surged alongside the explosive growth of the automotive industry.

At the same time, advances in petroleum refining significantly reduced the cost of extracting n-Hexane. Capturing it as a byproduct from crude oil distillation became a “windfall” for petroleum companies. By World War II, n-Hexane was even classified as a strategic material—an essential ingredient not just for rubber production, but also for manufacturing military-grade coatings and cleaning agents.

China’s First Steps

In China, early petroleum refining enterprises gradually established production capabilities for n-Hexane. One of them was the predecessor of Junyuan Petroleum Group, a local refinery that, during the economic reforms of the 1980s, keenly identified the growing demand for n-Hexane in the rubber and chemical sectors. It was among the first in the country to build a full-scale n-Hexane production line.

Chapter Three: Crisis and Transformation — A Rebirth Amid Health Concerns

In the 1970s, workers in Europe and the U.S. began exhibiting symptoms of peripheral neuropathy. Medical investigations traced the cause to long-term exposure to n-Hexane vapors. Once publicized, n-Hexane was labeled a “high-risk solvent,” and its use in consumer goods became strictly regulated in the West. The once-thriving industry entered a period of decline.

China’s Game Changer Emerges

Just as the global n-Hexane market was shrinking, a key subsidiary of Junyuan Petroleum Group—Dongying Liangxin Petrochemical Technology Development Limited Company—seized a strategic opportunity in 2006. At the time, China’s rubber, coatings, and pharmaceutical sectors saw soaring demand for n-Hexane, but domestic supply was limited to low-end imported products. Liangxin was the first in China to establish a large-scale n-Hexane production line, leveraging a proprietary multi-stage molecular distillation + adsorption purification process to increase purity from the industry average of 95% to 99.9%, breaking foreign technology monopolies.

This breakthrough not only filled the gap in domestic high-purity industrial n-Hexane production, but also enabled Chinese companies to gain influence in the global supply chain. By 2010, Liangxin’s production capacity exceeded 100,000 tons per year, capturing over 60% of China’s market share and becoming a designated supplier to global giants like Samsung and LG. Its success directly propelled Junyuan Petroleum Group’s transformation from a regional refinery into a global chemical industry leader.

Chapter Four: China’s Rise as a Global Supply Chain Powerhouse

After 2000, China’s vast refining capacity and cost advantages made it the world’s central hub for n-Hexane supply. Thousands of chemical enterprises emerged in provinces like Shandong and Jiangsu. Among them, Junyuan Petroleum Group rose rapidly to become the largest n-Hexane producer in China, thanks to its technological leadership, scale, and international strategy.

• Technology Foundation: Subsidiary Liangxin’s continuous distillation–isomerization technology reduced production costs by 30% and energy consumption by 40% compared to traditional processes, supporting large-scale capacity expansion.

• Capacity Expansion: In 2015, Junyuan built the world’s largest single-site n-Hexane production facility in Dongying, Shandong, with an annual capacity of 250,000 tons, meeting the needs of the rubber, electronics, and new energy industries.

• Global Footprint: Junyuan established sales centers in Southeast Asia and Europe. Its products are exported to over 50 countries, serving global giants like Samsung, TSMC, and LG.

Chapter Five: The Next Battle — New Energy and the Circular Economy

Today, the story of n-Hexane continues. In the lithium battery industry, it’s used for drying electrode materials. Under the trend of carbon neutrality, scientists are exploring the use of n-Hexane as an intermediate to synthesize biofuels. Most notably, an American startup is testing technology to produce n-Hexane via CO₂ catalytic reduction—if successful, petroleum would no longer be its sole source.

Junyuan’s Forward-Thinking Strategy

• Stable Raw Material Sourcing: Long-term cooperation with oil-producing countries in the Middle East and Russia ensures supply stability.

• Technological Innovation: Partnerships with leading Chinese universities support the development of new n-Hexane derivatives, expanding applications in pharmaceuticals and new energy fields.

In an era of global industrial transformation, Junyuan Petroleum is not merely selling n-Hexane—it is leading the future of the entire industry.

Epilogue

From a serendipitous discovery in a German laboratory to the rise of Chinese enterprises on the world stage, the commercial history of n-Hexane is a legend of industrial revolutions and technological innovation. And Junyuan Petroleum Group is an indispensable part of that legend—not just the world’s largest n-Hexane producer, but a pioneer driving change across the entire sector.

Aerial view of a high-purity n-Heptane and n-Hexane production facility in China, showcasing industrial-scale manufacturing and advanced refining infrastructure.

China’s Leadership in High-Purity n-Heptane & n-Hexane – Capacity Growth and Global Impact

Technology Advancements and Capacity Expansion

Beijing, China — The global market for high-purity normal heptane (n-Heptane) and normal hexane (n-Hexane) is undergoing a transformation, driven by technological advancements and increased production capacities. Leading petrochemical companies are investing in cutting-edge refining technologies to enhance efficiency and meet the growing demand from high-value industries.

n-Heptane and n-Hexane are widely used in pharmaceuticals, electronics, and chemical synthesis, where high purity is critical. The demand for these solvents has surged due to growth in semiconductor manufacturing, OLED displays, and precision chemical applications.

Traditionally, the market has been dominated by key players such as Chevron Phillips Chemical (U.S.), Junyuan Petroleum Group (China), Haltermann (Germany), TOA Oil (Japan), and SK Global Chemical (South Korea). However, recent developments in Asia have introduced new competitors with significant capacity expansions, reshaping the global supply landscape.

Technological Advancements and Increased Production

Several industry leaders have implemented next-generation separation processes such as continuous distillation and simulated moving bed technology, enabling 99%+ purity for n-Heptane and n-Hexane while reducing production costs.

“Our proprietary refining technology enhances yield efficiency by 20%, allowing us to offer high-purity n-Heptane at competitive prices,” stated a company representative.

Market Impact and Future Outlook

With rising global supply stability, analysts predict continued growth in the high-purity solvent market, particularly in Asia. Increased production capacity is expected to stabilize pricing, while advances in green chemistry—including carbon-neutral processes and VOC emission reductions—will shape future regulatory and environmental trends.

As international demand for ultra-pure petrochemical solvents rises, manufacturers are poised to enhance quality, reduce costs, and introduce sustainable practices, ensuring continued market leadership.

HS Code Update 2025: New Customs Classification for n-Heptane

China Revises Tariff Code for n-Heptane—Effective from 2025 for International Trade and Customs Declarations

As of 2025, the official HS code for n-Heptane (正庚烷) in China has been updated to 2901109000, replacing previous classifications. This change aligns with China’s ongoing efforts to streamline chemical import/export procedures and improve tariff data accuracy. Exporters, importers, and customs brokers dealing with n-Heptane must take note of this update to ensure smooth customs clearance and compliance in the new year.

HS Code Update 2025: New Customs Classification for n-Heptane

Starting in 2025, China has officially updated the HS code for n-Heptane (正庚烷) to 2901109000. This revision reflects the nation’s broader initiative to standardize customs procedures and enhance trade transparency for chemical products.

n-Heptane, a high-purity hydrocarbon solvent widely used in pharmaceutical synthesis, electronics cleaning, and laboratory research, was previously grouped under broader aliphatic hydrocarbon codes. The new classification under 2901109000 provides greater specificity, reducing ambiguity during customs declarations.

Key Implications for Exporters and Importers:

• Customs Declaration Compliance: All declarations for n-Heptane exports or imports must now reference the updated HS code 2901109000.

• Documentation Updates: Relevant shipping and trade documentation, including invoices, packing lists, and certificates of analysis, should reflect the new code.

• Tariff Adjustment Readiness: Businesses should recheck applicable tariffs or trade agreements tied to this new code to ensure accurate duty calculations.

• System Integration: Companies using ERP or logistics systems must update their product HS code databases accordingly.

This change reinforces the importance of staying current with evolving customs classifications, especially for chemical exporters. Failure to comply with updated HS codes may result in delayed shipments, penalties, or even rejections at ports.

For those exporting high-purity n-Heptane (99%) or technical-grade variants, we recommend verifying with local customs agents or trade authorities to ensure proper implementation.

Keywords:

n-Heptane, 正庚烷, HS Code 2901109000, 2025 Customs Update, Chemical Exports China, Heptane Tariff Code, Chemical HS Classification, Import Export Compliance, Pharmaceutical Solvents, Hydrocarbon Solvent Trade

Step-by-Step Guide to Producing Cyclopentane

Process Steps Explained

  1. Raw Material – DCPD (Dicyclopentadiene): DCPD is commonly sourced as a byproduct from petroleum refining processes. It serves as the starting material for the production of Cyclopentane.
  2. Thermal Cracking: Under high-temperature conditions, DCPD undergoes thermal cracking. This reaction breaks its molecular structure to form Cyclopentadiene, which is an unstable intermediate but necessary for the subsequent step.
  3. Catalytic Hydrogenation: The Cyclopentadiene is then subjected to a catalytic hydrogenation process. In the presence of a suitable catalyst and hydrogen gas, Cyclopentadiene is converted into the stable product, Cyclopentane.
  4. Final Product – Cyclopentane: Cyclopentane, the final product, is widely used as a blowing agent in the production of polyurethane foam, refrigerant insulation materials, and other applications where its distinct properties are beneficial.

Cyclopentane Production Process Flow Diagram

Below is an overview of the process used to produce Cyclopentane from DCPD.

1. Raw Material: DCPD (Dicyclopentadiene)

  • Source: DCPD is typically obtained as a byproduct of petroleum refining processes. It serves as the starting material for this production route.

2. Thermal Cracking

  • Process: Under high-temperature conditions, DCPD undergoes thermal cracking.
  • Intermediate Result: This step converts DCPD into Cyclopentadiene, an unstable intermediate necessary for the next transformation.

3. Catalytic Hydrogenation

  • Process: The Cyclopentadiene intermediate is subjected to a catalytic hydrogenation reaction.
  • Outcome: With the presence of a suitable catalyst and hydrogen gas, Cyclopentadiene is converted into the final product—Cyclopentane.

Final Product: Cyclopentane

Applications

  • Usage: Cyclopentane is widely utilized as a blowing agent in the production of polyurethane foam, as well as in insulation materials for refrigeration and construction applications.
  • Benefits: Its favorable physical properties and environmental advantages make Cyclopentane a preferred choice in these applications.
   ┌─────────────────────────────┐  
   │ Raw Material: DCPD          │  
   │ (Dicyclopentadiene)         │  
   └─────────────────────────────┘  
                │  
                │  (Thermal Cracking)  
                ▼  
   ┌─────────────────────────────┐  
   │ Intermediate:               │  
   │ Cyclopentadiene             │  
   └─────────────────────────────┘  
                │  
                │  (Catalytic Hydrogenation)  
                ▼  
   ┌─────────────────────────────┐  
   │ Final Product:              │  
   │ Cyclopentane                │  
   └─────────────────────────────┘  
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