Pentane – Thermophysical Properties
Chemical, physical and thermal properties of pentane, also called n-pentane. Phase diagram included.
Physical Properties The boiling points of the pentane isomers range from about 9 to 36 °C. As is the case for other alkanes, the more branched isomers tend to have lower boiling points.
Usually, n-Pentane is used as a refrigeration or air conditioning substance, effectively replacing substances such as fluorinated hydrocarbons and ammonia. Here are some of its potential uses: refrigerant R601, non-polar solvent polyethylene process medium, how to use Isopentane? Isopentane is widely used. Firstly, it is an important refrigerant, which is used as the mixed refrigerant component of condensation inducer and LNG in LLDPE unit of olefin plant; Used for blending octane number of oil products;
Usage: isopentane is widely used. First, it is an important refrigerant of olefin unit, condensation inducer of LLDPE unit and LNG mixed refrigerant components; Used for blending oil octane number; It is widely used in organic synthesis reactions and the separation and purification of organic compounds; Secondly, isopentane dehydrogenation can be made of isoprene and isoprene, and isopentanol is obtained by chlorination and hydrolysis. It is also an important raw material for organic synthesis. Isopentane can also be used with n-pentane in EPS (expandable polystyrene) blowing agent, or with cyclopentane as rigid polyurethane blowing agent. It is mainly used in organic synthesis and also as a solvent.
Cyclopentane, as a blowing agent in Polyurethane (PU) foams, is the most important raw material for high-performance insulation in refrigerators.
Pentane, C5H12, is a clear colorless liquid with a petroleum-like odor. It belongs to the organic class alkanes, and is naturally present in crude oils and condensates. It is a component of some fuels and is employed as a specialty solvent in the laboratory.
The boling point 36°C/97°F, and the vapors are heavier than air. Both the liquid an the vapor are flammable.
The phase diagram of pentane is shown below the table.
Chemical, physical and thermal properties of pentane:
Values are given for liquid at 25oC /77oF / 298 K and 1 bara, if not other phase, temperature or pressure given.
Property |
Value |
Unit |
|
Value |
Unit |
|
Value |
Unit |
|
Value |
Unit |
Autoignition temperature |
533 |
K |
|
260 |
°C |
|
500 |
°F |
|
|
|
Boiling Point |
309.2 |
K |
36.06 |
°C |
96.9 |
°F |
|
|
Critical density |
3.22 |
mol/dm3 |
232 |
kg/m3 |
0.450 |
slug/ft3 |
14.5 |
lb/ft3 |
Critical pressure |
3.36 |
MPa=MN/m2 |
33.6 |
bar |
33.2 |
atm |
487 |
psi=lbf/in2 |
Critical temperature |
469.8 |
K |
196.7 |
°C |
386.0 |
°F |
|
|
Critical volume |
311 |
cm3/mol |
0.00431 |
m3/kg |
2.22 |
ft3/slug |
0.0690 |
ft3/lb |
Density |
8606 |
mol/m3 |
620.9 |
kg/m3 |
1.205 |
slug/ft3 |
38.76 |
lb/ft3 |
Flammable, gas and liquid |
yes |
|
|
|
|
|
|
|
Flash point |
224 |
K |
-49 |
°C |
-56 |
°F |
|
|
Gas constant, individual, R |
115.2 |
J/kg K |
0.03201 |
Wh/(kg K) |
689.1 |
[ft lbf/slug °R] |
21.42 |
[ft lbf/lb °R] |
Gibbs free energy of formation (gas) |
-8 |
kJ/mol |
-111 |
kJ/kg |
-48 |
Btu/lb |
|
|
Heat (enthalpy) of combustion (gas) |
-3535 |
kJ/mol |
-48996 |
kJ/kg |
-21.1 |
Btu/lb |
|
|
Heat (enthalpy) of combustion (liquid) |
-3509 |
kJ/mol |
-48636 |
kJ/kg |
-20.9 |
Btu/lb |
|
|
Heat (enthalpy) of formation (gas) |
-147.0 |
kJ/mol |
-2037 |
kJ/kg |
-876 |
Btu/lb |
|
|
Heat (enthalpy) of formation (liquid) |
-173 |
kJ/mol |
-2398 |
kJ/kg |
-1031 |
Btu/lb |
|
|
Heat (enthalpy) of fusion at -202 °F/-130°C |
8.4 |
kJ/mol |
116 |
kJ/kg |
50.05 |
Btu/lb |
|
|
Heat (enthalpy) of sublimation, at -202°F/-130°C |
42 |
kJ/mol |
582 |
kJ/kg |
250 |
Btu/lb |
|
|
Heat (enthalpy) of evaporation |
26.4 |
kJ/mol |
366 |
kJ/kg |
157 |
Btu/lb |
|
|
Heat capacity, Cp (gas) |
120.0 |
J/mol K |
1.66 |
kJ/kg K |
0.397 |
Btu/lb°F or cal/g K |
|
|
Specific heat, Cp (liquid) |
168.0 |
J/mol K |
2.33 |
kJ/kg K |
0.556 |
Btu/lb°F or cal/g K |
|
|
Specific heat, Cv (liquid) |
125.0 |
J/mol K |
1.73 |
kJ/kg K |
0.414 |
Btu/lb°F or cal/g K |
|
|
Ionization potential |
10.34 |
eV |
|
|
|
|
|
|
log KOW (Octanol/Water Partition Coefficient) |
3.39 |
|
|
|
|
|
|
|
Melting point |
143.48 |
K |
-129.7 |
°C |
-201.4 |
°F |
|
|
Molecular Weight |
72.149 |
g/mol |
|
|
0.15906 |
lb/mol |
|
|
Solubility in water, at 25°C |
0.038 |
mg/ml |
|
|
|
|
|
|
Sound velocity |
1012 |
m/s |
|
|
3319 |
ft/s |
2267 |
mi/h |
Specific Gravity (gas) (relativ to air) |
2.48 |
|
|
|
|
|
|
|
Specific Gravity (liquid) (relativ to water) |
0.63 |
|
|
|
|
|
|
|
Specific Heat Ratio (gas) – CP/CV |
1.09 |
|
|
|
|
|
|
|
Specific Heat Ratio (liquid) – CP/CV |
1.34 |
|
|
|
|
|
|
|
Specific Volume |
0.0001162 |
m3/mol |
0.0016106 |
m3/kg |
0.8300514 |
ft3/slug |
0.0257988 |
ft3/lb |
Standard molar entropy, S° (gas) |
348 |
J/mol K |
4.82 |
kJ/kg K |
1.15 |
Btu/lb °F |
|
|
Standard molar entropy, S° (liquid) |
263 |
J/mol K |
3.65 |
kJ/kg K |
0.87 |
Btu/lb °F |
|
|
Surface tension |
16.0 |
dynes/cm |
0.016 |
N/m |
|
|
|
|
Thermal Conductivity |
0.111 |
W/m°C |
0.064135 |
Btu/hr ft °F |
|
|
|
|
Triple point pressure |
7.63*10-8 |
MPa=MN/m2 |
7.63*10-7 |
bar |
7.53*10-7 |
atm |
1.11*10-5 |
psi=lbf/in2 |
Triple point temperature |
143.5 |
K |
-129.7 |
°C |
-201.46 |
°F |
|
|
Vapor (saturation) pressure |
0.0685 |
MPa=MN/m2 |
514.0 |
mm Hg |
0.6762 |
atm |
9.94 |
psi=lbf/in2 |
Viscosity, dynamic (absolute) |
0.2224 |
cP |
149.4 |
[lbm /ft s*10-6] |
4.64 |
[lbf s/ft2 *10-6] |
|
|
Viscosity, kinematic |
0.358 |
cSt |
3.9 |
[ft2/s*10-6] |
|
|
|
|
Density and specific weight of liquid pentane at varying temperature and atmospheric pressure, SI and Imperial units:
Density units conversion of Pentane:
kilogram/cubic meter [kg/m3] = gram/liter [g/l], kilogram/liter [kg/l] = gram/cubic centimeter [g/cm3]= ton(metric)/cubic meter [t/m3], once/gallon(US liquid) [oz/gal(US liq)] pound/cubic inch [lb/in3], pound/cubic foot [lb/ft3], pound/gallon(UK) [lb/gal(UK)], pound/gallon(US liquid) [lb/gal(US liq)], slug/cubic foot [sl/ft3], ton(short)/cubic yard [ton(short)/yd3], ton(long)/cubic yard [yd3]
Pentane Phase Digaram