Pentane Formula, Properties, Uses and Isomers

Pentane Formula, Properties, Uses and Isomers

Pentane – Thermophysical Properties

Chemical, physical and thermal properties of pentane, also called n-pentane. Phase diagram included.

Physical Properties The boiling points of the pentane isomers range from about 9 to 36 °C. As is the case for other alkanes, the more branched isomers tend to have lower boiling points.

Usually, n-Pentane is used as a refrigeration or air conditioning substance, effectively replacing substances such as fluorinated hydrocarbons and ammonia. Here are some of its potential uses: refrigerant R601, non-polar solvent polyethylene process medium, how to use Isopentane? Isopentane is widely used. Firstly, it is an important refrigerant, which is used as the mixed refrigerant component of condensation inducer and LNG in LLDPE unit of olefin plant; Used for blending octane number of oil products;

Usage: isopentane is widely used. First, it is an important refrigerant of olefin unit, condensation inducer of LLDPE unit and LNG mixed refrigerant components; Used for blending oil octane number; It is widely used in organic synthesis reactions and the separation and purification of organic compounds; Secondly, isopentane dehydrogenation can be made of isoprene and isoprene, and isopentanol is obtained by chlorination and hydrolysis. It is also an important raw material for organic synthesis. Isopentane can also be used with n-pentane in EPS (expandable polystyrene) blowing agent, or with cyclopentane as rigid polyurethane blowing agent. It is mainly used in organic synthesis and also as a solvent.

Cyclopentane, as a blowing agent in Polyurethane (PU) foams, is the most important raw material for high-performance insulation in refrigerators. 

Pentane, C5H12, is a clear colorless liquid with a petroleum-like odor. It belongs to the organic class alkanes, and is naturally present in crude oils and condensates. It is a component of some fuels and is employed as a specialty solvent in the laboratory.

The boling point 36°C/97°F, and the vapors are heavier than air. Both the liquid an the vapor are flammable.

The phase diagram of pentane is shown below the table.

Chemical, physical and thermal properties of pentane:
Values are given for liquid at 25oC /77oF / 298 K and 1 bara, if not other phase, temperature or pressure given.

Property Value Unit Value Unit Value Unit Value Unit
Autoignition temperature 533 K 260 °C 500 °F
Boiling Point 309.2 K 36.06 °C 96.9 °F
Critical density 3.22 mol/dm3 232 kg/m3 0.450 slug/ft3 14.5 lb/ft3
Critical pressure 3.36 MPa=MN/m2 33.6 bar 33.2 atm 487 psi=lbf/in2
Critical temperature 469.8 K 196.7 °C 386.0 °F
Critical volume 311 cm3/mol 0.00431 m3/kg 2.22 ft3/slug 0.0690 ft3/lb
Density 8606 mol/m3 620.9 kg/m3 1.205 slug/ft3 38.76 lb/ft3
Flammable, gas and liquid yes
Flash point 224 K -49 °C -56 °F
Gas constant, individual, R 115.2 J/kg K 0.03201 Wh/(kg K) 689.1 [ft lbf/slug °R] 21.42 [ft lbf/lb °R]
Gibbs free energy of formation (gas) -8 kJ/mol -111 kJ/kg -48 Btu/lb
Heat (enthalpy) of combustion (gas) -3535 kJ/mol -48996 kJ/kg -21.1 Btu/lb
Heat (enthalpy) of combustion (liquid) -3509 kJ/mol -48636 kJ/kg -20.9 Btu/lb
Heat (enthalpy) of formation (gas) -147.0 kJ/mol -2037 kJ/kg -876 Btu/lb
Heat (enthalpy) of formation (liquid) -173 kJ/mol -2398 kJ/kg -1031 Btu/lb
Heat (enthalpy) of fusion at -202 °F/-130°C 8.4 kJ/mol 116 kJ/kg 50.05 Btu/lb
Heat (enthalpy) of sublimation, at -202°F/-130°C 42 kJ/mol 582 kJ/kg 250 Btu/lb
Heat (enthalpy) of evaporation 26.4 kJ/mol 366 kJ/kg 157 Btu/lb
Heat capacity, Cp (gas) 120.0 J/mol K 1.66 kJ/kg K 0.397 Btu/lb°F or cal/g K
Specific heat, Cp (liquid) 168.0 J/mol K 2.33 kJ/kg K 0.556 Btu/lb°F or cal/g K
Specific heat, Cv (liquid) 125.0 J/mol K 1.73 kJ/kg K 0.414 Btu/lb°F or cal/g K
Ionization potential 10.34 eV
log KOW (Octanol/Water Partition Coefficient) 3.39
Melting point 143.48 K -129.7 °C -201.4 °F
Molecular Weight 72.149 g/mol 0.15906 lb/mol
Solubility in water, at 25°C 0.038 mg/ml
Sound velocity 1012 m/s 3319 ft/s 2267 mi/h
Specific Gravity (gas) (relativ to air) 2.48
Specific Gravity (liquid) (relativ to water) 0.63
Specific Heat Ratio (gas) – CP/CV 1.09
Specific Heat Ratio (liquid) – CP/CV 1.34
Specific Volume 0.0001162 m3/mol 0.0016106 m3/kg 0.8300514 ft3/slug 0.0257988 ft3/lb
Standard molar entropy, S° (gas) 348 J/mol K 4.82 kJ/kg K 1.15 Btu/lb °F
Standard molar entropy, S° (liquid) 263 J/mol K 3.65 kJ/kg K 0.87 Btu/lb °F
Surface tension 16.0 dynes/cm 0.016 N/m
Thermal Conductivity 0.111 W/m°C 0.064135 Btu/hr ft °F
Triple point pressure 7.63*10-8 MPa=MN/m2 7.63*10-7 bar 7.53*10-7 atm 1.11*10-5 psi=lbf/in2
Triple point temperature 143.5 K -129.7 °C -201.46 °F
Vapor (saturation) pressure 0.0685 MPa=MN/m2 514.0 mm Hg 0.6762 atm 9.94 psi=lbf/in2
Viscosity, dynamic (absolute) 0.2224 cP 149.4 [lbm /ft s*10-6] 4.64 [lbf s/ft2 *10-6]
Viscosity, kinematic 0.358 cSt 3.9 [ft2/s*10-6]

Density and specific weight of liquid pentane at varying temperature and atmospheric pressure, SI and Imperial units:

Density units conversion of Pentane:

kilogram/cubic meter [kg/m3] = gram/liter [g/l], kilogram/liter [kg/l] = gram/cubic centimeter [g/cm3]= ton(metric)/cubic meter [t/m3], once/gallon(US liquid) [oz/gal(US liq)] pound/cubic inch [lb/in3], pound/cubic foot [lb/ft3], pound/gallon(UK) [lb/gal(UK)], pound/gallon(US liquid) [lb/gal(US liq)], slug/cubic foot [sl/ft3], ton(short)/cubic yard [ton(short)/yd3], ton(long)/cubic yard [yd3]

  • 1 g/cm3 = 1 kg/l = 1000 kg/m3 = 62.428 lb/ft3 = 0.03613 lb/in3 = 1.9403 sl/ft3 = 10.0224 lb/gal(UK) = 8.3454 lb/gal(US liq) = 0.5780 oz/in= 0.7525 ton(long)/yr3
  • 1 g/l = 1 kg/m3 = 0.001 kg/l = 0.000001 kg/cm3 = 0.001 g/cm3 = 0.99885 oz/ft3  = 0.0005780 oz/in3 = 0.16036 oz/gal(UK) = 0.1335 oz/gal(US liq) = 0.06243 lb/ft3 = 3.6127×10-5 lb/in3 = 1.6856 lb/yd3 = 0.010022 lb/gal(UK) = 0.0083454 lb/gal(US liq) = 0.0007525 ton(long)/yd= 0.0008428 ton(short)/yd3
  • 1 kg/l = 1 g/cm3 = 1000 kg/m3 = 62.428 lb/ft3 = 0.03613 lb/in3 = 1.9403 sl/ft3 = 8.3454 lb/gal(US liq) = 0.5780 oz/in= 0.7525 ton(long)/yr3
  • 1 kg/m3 = 1 g/l = 0.001 kg/l = 0.000001 kg/cm3 = 0.001 g/cm3 = 0.99885 oz/ft3  = 0.0005780 oz/in3 = 0.16036 oz/gal(UK) = 0.1335 oz/gal(US liq) = 0.06243 lb/ft3 = 3.6127×10-5 lb/in3 = 1.6856 lb/yd3 = 0.010022 lb/gal(UK) = 0.008345 lb/gal(US liq) = 0.0007525 ton(long)/yd = 0.0008428 ton(short)/yd
  • 1 lb/ft3 = 27 lb/yd3 = 0.009259 oz/in= 0.0005787 lb/in= 16.01845 kg/m3 = 0.01602 g/cm3  = 0.1605 lb/gal(UK) = 0.1349 lb/gal(US liq) = 2.5687 oz/gal(UK) = 2.1389 oz/gal(US liq) = 0.01205 ton(long)/yd3 = 0.0135 ton(short)/yd3
  • 1 lb/gal(UK) = 0.8327 lb/gal(US liq) = 16 oz/gal(UK) = 13.323 oz/gal(US liq) = 168.179 lb/yd3 = 6.2288 lb/ft3 = 0.003605 lb/in3 = 0.05767 oz/in = 99.7764 kg/m3 = 0.09977 g/cm3  = 0.07508 ton(long)/yd3 = 0.08409 ton(short)/yd3
  • 1 lb/gal(US liq) = 1.2009 lb/gal(UK) = 19.215 oz/gal(UK) = 16 oz/gal(US liq) = 201.97 lb/yd3 = 7.4805 lb/ft3 = 0.004329 lb/in3 = 0.06926 oz/in = 119.826 kg/m3 = 0.1198 g/cm3  = 0.09017 ton(long)/yd3 = 0.1010 ton(short)/yd3
  • 1 lb/in3 = 1728 lb/ft3 = 46656 lb/yd3 = 16 oz/in= 27680 kg/m3 = 27.680 g/cm3  = 277.419 lb/gal(UK) = 231 lb/gal(US liq) =4438.7 oz/gal(UK) = 3696 oz/gal(US liq) = 20.8286 ton(long)/yd3 = 23.3280 ton(short)/yd3
  • 1 oz/gal(UK) =  0.8327 oz/gal(US liq) = 6.2360 kg/m3 = 6.2288 oz/ft3 = 0.3893 lb/ft3 = 10.5112 lb/yd3
  • 1 oz/gal(US liq) = 1.2009 oz/gal(UK) = 7.4892 kg/m3 = 7.4805 oz/ft3 = 0.4675 lb/ft3 = 12.6234 lb/yd3
  • 1 sl/ft3 = 515.3788 kg/m3 = 514.7848 oz/ft3 = 0.2979 oz/in3 = 32.1741 lb/ft3 = 82.645 oz/gal(UK) = 68.817 oz/gal(US liq) 
  • 1 ton(long)/yd3 = 1.12 ton(short)/yd3 = 1328.94 kg/m3 = 0.7682 oz/in3 = 82.963 lb/ft3 = 2240 lb/yd3 = 2.5786 sl/ft3 = 13.319 lb/gal(UK) = 11.0905 lb/gal(US liq)
  • 1 ton(short)/yd3 = 0.8929 ton(long)/yd3 = 1186.55 kg/m3 = 0.6859 oz/in3 = 74.074 lb/ft3 = 2000 lb/yd3 = 2.3023 sl/ft3 = 11.8921 lb/gal(UK) = 9.9023 lb/gal(US liq)


Pentane Phase Digaram

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