In 2022, the price changes of pentane, hexane and heptane during the new year’s Day holiday and the prospect of the trend after the holiday. On the eve of the New Year’s Day holiday, domestic pentane and hexane pushed up all the way, with an increase of nearly 100 yuan per ton. According to the real-time exchange rate of RMB against the US dollar today, it is about US $16 / ton. The price of n-Heptane products fell, with a decrease of up to 500 yuan per ton, about US $78/MT. Supply tightening is the main boost. On the one hand, Junyuan Petroleum Group, a leading manufacturer of Pentane, Hexane and Heptane, took the lead in increasing the quotation while controlling the volume of shipments; On the other hand, the replenishment of domestic trade ships is limited, and the impact on the delayed arrival of imported ships is small. The inventory in Qingdao and Shanghai ports continues to be less than 30,000 tons. The cargo holders have no shipping pressure, have a positive attitude, push up actively, and focus all the way up.
During the New Year’s Day holiday, the market atmosphere was relatively quiet, and most operators withdrew from the market to wait and see, waiting for the market to become clear after the festival.
Changes in main factors affecting price fluctuations
Cost Side
Firstly, based on the analysis of the price trend of main raw materials for pentane, hexane and heptane production, the price of naphtha rose before the new year’s Day holiday. Considering the decrease of imported cargoes from January to February, the new n-Heptane unit is put into operation, and coincides with the extension of the unloading period of n-Heptane import ships on the shore, n-Heptane is expected to be transferred to the warehouse removal stage; However, it should also be noted that after the new n-Heptane production unit is put into operation, the negative pressure of non integrated n-Heptane caused by intensified industry competition will directly pull down the price of n-Heptane. Therefore, it is expected that in the first ten days of January, n-Heptane will mainly fluctuate at a low level, focusing on the shipping situation in Shanghai and Qingdao and the production process of downstream n-Heptane.
Secondly, considering the average contract price, the starting point of the average price of Pentane and Hexane in January is high, and there is little room for contract households to make profit and ship goods, so it needs to be treated with caution.
Supply Side
From the perspective of domestic supply, it is reported that the major pentane, hexane and heptane manufacturers planned to store, shut down and overhaul their units in January, and the contract has corresponding reduction expectations. In addition, considering the immediate demand or stock mood in the first ten days, it is expected that there will be little pressure on domestic goods supply in the first ten days.
Pentane Blends
Analysis on price fluctuation of pentane products in 2021
Hydrocarbon prices have been stable in the last three days. Today is the last day of China's New Year's Day holiday. Each chemical enterprise has not started yet, and the order delivery of each solvent factory is carried out as usual. The staff of the sales department, freight forwarding enterprise, logistics enterprise and the production and loading and unloading team of the factory are usually on duty on a 7 / 24 rotation all year round.
Analysis on price fluctuation of pentane products in 2021
In 2021, the price of domestic pentane products rose across the board compared with last year. The price trend of the whole year is obvious from the figure, which is higher than that of the previous two years. Especially at the end of October, the price soared to a historic high, and the annual low was at the beginning of the year. Throughout the year, the supply and demand factors of n-Pentane, Isopentane, Foaming Agent and Cyclopentane changed a lot. In February and March, the extremely cold weather in Europe and America disturbed the supply pattern and flow direction, and the production units at home and abroad were unstable. In the second half of the year, the domestic units stopped periodically, the supply decreased, and the market price gradually showed an upward trend. With the off-season of downstream demand, the export cost increased, the market focus returned, and the phased decline at the end of the year ended.
Throughout the year, in addition to the fundamentals of supply and demand, the market is still affected by many factors: the domestic epidemic situation is effectively controlled, but the foreign epidemic situation is continuous, which has a certain inhibition on exports and shipping, and the crude oil market is volatile. In the second half of the year, the global market boom is gradually depressed, and it is difficult for the solvent industry terminal to improve. The demand side is gradually unable to bear high-priced raw materials, so it is "GivingUp" waiting at the end of the year, Hydrocarbon production plants are passive under pressure.
In the twinkling of an eye, the Spring Festival in 2022 is coming. China's Spring Festival is as important as Christmas in the West. It is believed that many people are looking forward to returning home to reunite with their relatives, the annual Spring Festival transportation is about to start, and college students are about to have a winter vacation. The Spring Festival is a festival that every Chinese people look forward to.
Pentane
Pentane is an organic compound with the formula C₅H₁₂—that is, an alkane with five carbon atoms. The term may refer to any of three structural isomers, or to a mixture of them: in the IUPAC nomenclature, however, pentane means exclusively the n-pentane isomer; the other two are called isopentane and neopentane.
Hexane
n-Heptane
Octane
Description
Octane is a hydrocarbon and an alkane with the chemical formula C₈H₁₈, and the condensed structural formula CH₃(CH₂)₆CH₃. Octane has many structural isomers that differ by the amount and location of branching in the carbon chain.Due to governmental demands regarding the industrial output of ozone- depleting compounds, foam boards are now produced using various pentane isomers as blowing agents. Pentane isomers are normal pentane, isopentane, and cyclopentane.
- Blend iso/n-pentane (25 – 75%) : It is a mixture of 25% of isopentane and 75% of n-pentane.
- Blend iso/n-pentane (20 – 80%) : It is a mixture of 20% of isopentane and 80% of n-pentane.
- Blend iso/n-pentane (30 – 70%) : It is a mixture of 30% of isopentane and 70% of n-pentane.
- Blend Iso/n-Pentane (40– 60%) : It is a mixture of 40% of Isopentane and 60% of n-Pentane.
Product Knowledge Sharing Today:
Chemical industry chain: raw materials → intermediates → consumer goods
Analyze the situation from the chemical industry chain. The direction of basic chemical industry university can be analyzed from syllogism: upstream raw materials, intermediate products and downstream conditions. Upstream raw materials are simply summarized as crude oil, coal mines and various chemical minerals (lithium, potassium and phosphate). Downstream can be summarized in four words: food, clothing, housing and transportation. All chemical sub industries can implement these four words. Clothing: textile industry, chemical products related to the textile industry, as well as fibers and polyester used in the textile industry. Food: chemical food processing industry, agrochemical sector, nitrogen, phosphorus and potassium, compound fertilizer, pesticides, food additives and medicine. Housing: real estate, real estate related, such as household appliances. OK: automobile, high-speed railway, rubber sub industry in tires, etc.
What are Hydrocarbons?
Core tip: Hydrocarbon products are widely used in daily production and life. Hydrocarbons are divided into alkanes, cycloalkanes and aromatic hydrocarbons. HCR433B hydrocarbon refrigerant is the most representative in commercial life, while HCR436A hydrocarbon refrigerant is the most representative in automobile.
“Hydrocarbon” is a common name for hydrocarbons. Organic compounds composed only of carbon and hydrogen are called hydrocarbons, also known as hydrocarbons. It reacts with chlorine, bromine vapor and oxygen to produce hydrocarbon derivatives. Saturated hydrocarbons (and benzene) do not react with strong acids, bases and strong oxidants (such as potassium permanganate), but unsaturated hydrocarbons (olefins, alkynes and benzene homologues) can be oxidized or react with hydrogen halide. There are many kinds of hydrocarbons, and there are more than 2000 kinds of hydrocarbons with known structures. Hydrocarbon is the parent of organic compounds. Other kinds of organic compounds can be regarded as derivatives generated by the substitution of one or more hydrogen atoms in hydrocarbon molecules by atoms or atomic groups of other elements.
Hydrocarbons in petroleum
Hydrocarbon in Chinese is the abbreviation of hydrocarbon, which is composed of “fire” in “carbon” and “巠” in “hydrogen”. Hydrocarbons are divided into saturated hydrocarbons and unsaturated hydrocarbons. Most hydrocarbons in petroleum are saturated hydrocarbons, while unsaturated hydrocarbons such as ethylene and acetylene can be obtained only in the process of petroleum processing. There are three types of hydrocarbons in petroleum:
(1) Alkane
It is a chain hydrocarbon with single bond between carbon atoms. Due to the different number of carbon and hydrogen atoms that make up hydrocarbons, petroleum contains hydrocarbon molecules with great and small differences. Alkanes are named according to the carbon atoms and number contained in the molecule. Those with less than 10 carbon atoms are represented by a, B, C, D, e, hexane, heptane, octane, nonane and decane from 1 to 10. Those with more than 11 carbon atoms are represented by numbers. Alkanes in petroleum include normal alkanes and isoalkanes. The content of n-alkanes in paraffin based petroleum is high; The content of isoalkanes in pitch based petroleum is high. Alkanes are also called alkane hydrocarbons. The general formula of the molecular formula of alkanes is CnH2n + 2, where n represents the number of carbon atoms in the molecule. 2n + 2 represents the number of hydrogen atoms. Under normal temperature and pressure, C1-C4 alkanes are gaseous and exist in natural gas; C5-c16 alkanes are liquid and the main component of petroleum; Alkanes above C16 are solid.
(2) Cycloalkanes
As the name suggests, it is a ring structure. The most common is a ring composed of five or six carbon atoms. The former is called cyclopentane and the latter is called cyclohexane. The general formula of the molecular formula of cycloalkanes is CnH2n. Cycloalkanes are also called cycloalkanes.
(3) Aromatic hydrocarbon
Also known as aromatic hydrocarbons. It is generally composed of one or more six membered rings with special structure. The simplest aromatic hydrocarbons are benzene, toluene and xylene. They can be obtained from the production of platinum reforming unit in the oil refining process. The general formula of the molecular formula of aromatic hydrocarbons is CNH2N-6.
To sum up, hydrocarbons exist in many things, such as fuels and cleaning agents, and are widely used in daily life.
The organic solvent purification system can process solvents:
Aromatic and aliphatic hydrocarbons: Pentane, n-Hexane, Cyclohexane, n-Heptane, Toluene, Benzene
Ethers: ether, tetrahydrofuran, dimethyl ether
Chlorinated solvent: dichloromethane, chloroform, chlorobenzene
Amine solvents: triethylamine, pyridine, diisopropyl ethyl amine
Alcohol: methanol, ethanol
Other general solvents: acetonitrile, dimethylformamide, dimethyl sulfoxide, acetone
2021/12/31. USD TO CNY TODAY.
The price of foaming agent rose slightly today, among which the price of foam blowing agent with high Isopentane content increased by 0.81 percentage points, and the price of foam blowing agent with high n-Pentane content increased by 0.85 percentage points. The price returned to its position on December 24.
The prices of other key products such as n-Pentane, Isopentane, n-Heptane and n-Hexane remain unchanged today.
Chemical Market Focus
U.S. commercial crude oil inventory and refined oil inventory decreased, and international oil prices continued to rise, but the epidemic in Europe and the United States severely restrained the increase again. NYMEX crude oil futures 02 contract 76.56, up $0.58/barrel or 0.76%; Ice oil distribution futures 02 contract 79.23 rose $0.29/barrel, or 0.37%.
Industry News
◎ judging from the US economic data, crude oil prices rose and fell
Recently, the US dollar index has weakened, reaching 96.09 on December 27, down 0.50% from December 17. The decline of the dollar mainly stems from: on December 20, Goldman Sachs Group lowered its forecast for U.S. economic growth because Democratic Senator manqin said he would not support the core content of President Biden’s economic agenda, that is, the $2 trillion tax and expenditure plan. Manchin’s statement actually killed the Democratic Party’s plan to pass the bill called build back better. Economists at Goldman Sachs said that if the bill could not be passed, it would have a negative impact on U.S. economic growth and would make the U.S. economy face the dilemma of slowing down in 2022. The weakening dollar supported the rise of crude oil prices to a certain extent.
◎ domestic LNG price in terms of apparent consumption
Affected by the epidemic situation, the comprehensive statistics of domestic apparent natural gas consumption from January to February 2020 is 52.7 billion cubic meters. Without splitting, the annual apparent natural gas consumption in 2020 is 320.38 billion cubic meters. Except for the epidemic situation at the beginning of the year and the Spring Festival factors, it is relatively stable throughout the year and increases in the heating season. There will be great changes in 2021. Although the overall consumption increases greatly, the consumption growth rate is unstable. As of October 2021, the apparent consumption of domestic natural gas totaled 302.893 billion cubic meters, an increase of 24.51% over the same period last year. And this year, the apparent consumption in October near the heating season decreased by 2.34% compared with September. The reason is that under the demand expectation and supply guarantee requirements of this year’s heating season, the domestic natural gas reserve work is carried out in advance, and the overall reserve is relatively sufficient. With the promotion of carbon peak and carbon neutralization, the strengthening of environmental protection work by local governments greatly limits the industrial demand, so the demand shrinks near the heating season.
◎ needle coke market summary in November
In November 2021, the import volume of needle coke was 20900 tons, an increase of 11% month on month. Among them, oil measures are 8700 tons, accounting for 41.6%, and coal measures are 12200 tons, accounting for 58.4%. From January to November 2021, the cumulative import volume of needle coke is about 205400 tons, and the oil series is 97500 tons, accounting for 47%. Coal measures account for 10.79%, accounting for 52%
◎ liquefied gas: the market rebounded at a low level after ether appeared on the positive support of supply and demand
The supply of some oil producing countries has decreased and the market demand prospect has been better supported. The international crude oil trend is strong, which has obvious positive support for the relevant industrial chains in the region. However, as the end of the year is approaching, there is a certain demand for inventory discharge by enterprises, and the market atmosphere tends to be conservative. It is expected that the market will maintain stability in the short term, and the power for both rise and fall is insufficient. After the year or due to the centralized replenishment of downstream goods, The market has a “good start” again, but under the influence of policy, there is uncertainty. Follow up, pay close attention to the startup and shutdown of upstream and downstream devices.
◎ game between cost and demand, stalemate in polyester filament Market
With strong cost support and weak demand as a foregone conclusion, polyester filament needs to pay more attention to its own fundamental data. As we all know, the load of direct spinning factories in the Spring Festival is higher than that of looms, so the inventory of polyester filament factories from January to February is expected. According to the market understanding, the inventory of some polyester filament factories has been at a high level. Near the Spring Festival, the factory or machine price exchange is not ruled out. At this time, polyester filament is in a shock downward trend in the game of cost and demand, or dragged down by demand.
◎ the supply of polyester bottles and chips is reduced, and the spot in the market is still tight
From the order receiving situation of polyester bottle chip manufacturers, the order receiving amount of the factory has decreased recently. Since mid September, due to the influence of dual control, some production enterprises have limited operation and reduced supply, and the spot circulation of polyester bottles and chips shows signs of tightening. In addition, the increase in foreign trade shipments has exacerbated the tense atmosphere of spot circulation. The large downstream soft drink manufacturers will advance the procurement cycle and the centralized purchase time to November. In the fourth quarter, according to the past performance, the demand is off-season, and the bottle chip factory is overhauled during this period. However, this year is different from previous years. The off-season is “not light”, and the demand side makes collective efforts. As a result, the polyester bottle chip factory has no spot to sell and can only sell far month futures. Last weekend, a 600000 ton unit of a large factory in East China was overhauled as planned, the supply was further reduced, and the price of polyester bottles and chips rose steadily.
◆ industry newsletter
◎ EU economic Commissioner gentiloni said that the EU is considering amending the stability and growth pact to no longer set a unified debt ceiling and allow member states to set a reasonable debt scale according to their national conditions. Since March 2020, EU member states have unanimously decided to suspend the implementation of the EU stability and growth pact until the end of 2022.
◎ the US merchandise trade deficit in November increased to US $97.8 billion, expanding to a record high. Among them, the import volume increased by 4.7% to a record high of US $252.4 billion; Exports fell to $154.7 billion. In addition, US wholesale inventory increased by 1.2% and retail inventory increased by 2% in November, the largest increase since 1992.
◎ the second-hand housing contract volume index of the United States unexpectedly fell by 2.2% in November, while it fell by 2.7% year-on-year. The real estate market, boosted by strong demand and low borrowing costs, began to cool towards the end of the year, and high house prices and limited inventory still put pressure on house purchase activities.
◎ the Ministry of industry and information technology and other six departments jointly issued the implementation plan for the recycling of industrial wastewater, which proposed to strive to achieve the reuse rate of industrial water above Designated Size of about 94% by 2025, and the water consumption of 10000 yuan of industrial added value decreased by 16% compared with 2020. Focus on key industries such as petrochemical and chemical industry, iron and steel, nonferrous metals, papermaking, textile and food, and implement the action to improve the recycling of wastewater.
◎ according to the 14th five year plan for copyright work issued by the national copyright administration, by 2025, the construction of a copyright power will have achieved remarkable results, the number of works registered across the country will exceed 5 million, and the added value of the copyright industry will increase to about 7.5% of GDP.
Thursday (December 30)
06:00 Singapore’s total fuel inventory for the week ended December 29 (10000 barrels)
21:30 US initial jobless claims for the week ended December 25 (10000)
At 21:30, the number of Americans who renewed their claims for unemployment benefits for the week ended December 18 (10000)
22:45 Chicago PMI in December
Today, the price of n-Heptane plunged by 6.58 percentage points. The price of pentane blowing agent increased by 0.85% on December 24, and then decreased by 0.84% on December 28. The continuous rise and fall of prices has always been the characteristic of foaming agent products, and the market price fluctuates too much due to the cost of raw materials.
The recent favorable factors in the crude oil market have the upper hand, and the crude oil price may maintain a strong trend and continue to operate at a relatively high level.
Date/Time | 12/22/2021 | 12/23/2021 | 12/24/2021 | 12/25/2021 | 12/26/2021 | 12/27/2021 | 12/28/2021 |
10:30 AM | 10:00 AM | 09:38 AM | 09:35 AM | 09:50 AM | 09:37 AM | 09:20 AM | |
n-Pentane,95% CAS# 109-66-0 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
n-Pentane,99% CAS# 109-66-0 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
Isopentane,95% CAS# 78-78-4 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
Isopentane,99% CAS# 78-78-4 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
Blowing Agent | 0.00% | 0.00% | +0.85% | 0.00% | 0.00% | 0.00% | -0.84% |
Cyclopentane CAS# 287-92-3 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
n-Hexane,60% CAS# 110-54-3 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
n-Hexane,70% CAS# 110-54-3 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
n-Hexane,80% CAS# 110-54-3 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
n-Hexane,90% CAS# 110-54-3 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
n-Hexane,99% CAS# 110-54-3 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
n-Heptane,99% CAS# 142-82-5 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | -6.58% |
n-Octane,99% CAS# 111-65-9 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
D-20 Fluid CAS# 64742-94-5 |
0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% | 0.00% |
Pentane Foaming Agent
How is expandable polystyrene produced in the manufacturing process?
Expandable Polystyrene (EPS) Production and Manufacturing Process Expandable polystyrene (EPS) is produced in a suspension process by adding a blowing agent, usually pentane, which causes resin to foam during moulding. The process may be performed as a single step or a two step process.
Founded in January 2009 and located in Dongying City, Shandong Province, Dongying Liangxin Petroleum Technology Development Co., Ltd. is a wholly-owned subsidiary of Junyuan Petroleum Group and the first professional company in China to produce and sell pentane foaming agent. Based on the development needs, the company purchased the production base in 2014, rapidly expanded the product types and output, and formed a joint-stock company of petroleum fine chemicals mainly engaged in hydrocarbon environmental protection foaming agents, refrigerants and clean gasoline additives.
Pentane foaming agent is extremely flammable. Its vapor and air can form an explosive mixture. It is very easy to burn and explode in case of open fire and high heat Strong reaction with oxidant and even combustion Liquid is lighter than water and insoluble in water. It can drift and spread to a distance with water and cause combustion in case of open fire In the fire scene, heated containers are in danger of explosion.
The new technology of hydrobenzene removal with pentane foaming agent is to remove impurity benzene from raw materials under mild conditions (temperature 130 ~ 150 ℃, pressure 0.3 ~ 0.5MPa) and nickel catalyst. This process is used in the production of blowing agent of Junyuan Petroleum Group. After the application of this technology, the benzene content in pentane blowing agent is reduced from 300mg / kg to 5mg / kg, which has good economic and social benefits.
Pentane as foaming agent is mainly used to foam polyurethane and styrene. In pentane foaming agent, pentane is mainly n-pentane and isopentane, and when the proportion reaches more than 99%, it can be used as styrene foaming agent, and the finished product is EPS.
In addition, n-pentane can be used for foaming of building plates. The main purpose of making polyurethane foaming agent is cyclopentane, which is mainly used for foam in the refrigerator door. When you go home, you can see the label of cyclopentane on your refrigerator. This is mainly due to the cavitation of ozone layer before foaming, but later replaced by 141b, but it is still polluted. Pentane will not be cleaned. Pentane has a low density of about 0.62, which is flammable and volatile. As a foaming agent, it uses its volatile characteristics to leave small holes in styrene or polyurethane. It should belong to physical foaming without chemical reaction. Up to now, EPS foaming with pentane has been a mature system, while polyurethane foaming with cyclopentane is still developing. Because China pays close attention to industrial safety, few manufacturers can change the foaming agent from 141b to cyclopentane for polyurethane, mainly large refrigerator factories such as Haier and Hisense.
Pentane in pentane foaming agent is mainly composed of n-pentane and isopentane, and when the proportion reaches more than 99%, it can be used as styrene foaming agent and finished EPS; In addition, n-pentane can be used for foaming of building panels. When making polyurethane foaming agent, it is mainly cyclopentane, which is mainly used for foam in refrigerator door body.
Polystyrene foam board, also known as foam board and EPS board, is a white object heated by polystyrene beads containing volatile liquid blowing agents and preheated by heating. It has a structural feature of micro closed holes. It is mainly used for building walls, roof insulation, composite board insulation, cold storage, air conditioning, vehicles, ships, thermal insulation, floor heating. Decoration and carving are widely used.